A practical Ti-salen catalyst based on dimeric salen ligand for asymmetric addition of trimethylsilyl cyanide to aldehydes

	A practical Ti-salen catalyst based on dimeric salen ligand for asymmetric addition of trimethylsilyl cyanide to aldehydes
Department	羰基合成与选择氧化国家重点实验室
	Lv CW(吕成伟); Xu DQ(徐大乾); Wang SF(王寿峰); Miao CX(苗成霞); Xia CG(夏春谷); Sun W(孙伟)
	2011
Source Publication	Catal. Commun.
ISSN	1566-7367
Volume	12 Issue:13 Pages:1242-1245
Abstract	A dimeric salen ligand derived from L-tartaric acid was synthesized through linking two salen units with 1,6- dibromohexane. The corresponding Ti complex was proved to be an efficient catalyst for asymmetric addition of trimethylsilyl cyanide to aldehydes, providing the corresponding optically active trimethylsilyl ether of cyanohydrins with moderate to good enantiomeric excesses and excellent yields under relatively low catalyst loading condition.
Keyword	Salen Asymmetric Silylcyanation Aldehydes Titanium
Subject Area	仿生与生物催化
Funding Organization	the Chinese Academy of Sciences and National Natural Science Foundation of China (21073210, 20873166).
Indexed By	SCI
Language	英语
Funding Project	均相催化研究组 ; 生物与仿生催化研究组
Citation statistics	Cited Times:16[WOS] [WOS Record] [Related Records in WOS]
Document Type	期刊论文
Identifier	http://ir.licp.cn/handle/362003/280
Collection	羰基合成与选择氧化国家重点实验室（OSSO）
Corresponding Author	Sun W(孙伟)
Recommended Citation GB/T 7714	Lv CW,Xu DQ,Wang SF,et al. A practical Ti-salen catalyst based on dimeric salen ligand for asymmetric addition of trimethylsilyl cyanide to aldehydes[J]. Catal. Commun.,2011,12(13):1242-1245.
APA	吕成伟,徐大乾,王寿峰,苗成霞,夏春谷,&孙伟.(2011).A practical Ti-salen catalyst based on dimeric salen ligand for asymmetric addition of trimethylsilyl cyanide to aldehydes.Catal. Commun.,12(13),1242-1245.
MLA	吕成伟,et al."A practical Ti-salen catalyst based on dimeric salen ligand for asymmetric addition of trimethylsilyl cyanide to aldehydes".Catal. Commun. 12.13(2011):1242-1245.

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