Preparation of Cu/ZnO/Al2O3 Catalyst for CO2 Hydrogenation to Methanol by CO2 Assisted Aging | |
Department | 羰基合成与选择氧化国家重点实验室 |
Wang DJ(王丹君); Tao FR(陶芙蓉); Zhao HH(赵华华); Song HL(宋焕玲); Chou LJ(丑凌军) | |
2011 | |
Source Publication | Chin. J. Catal. |
ISSN | 1872-2067 |
Volume | 32Pages:1452-1456 |
Abstract | A Cu/ZnO/Al2O3 catalyst prepared by adding CO2 during the aging step was used for methanol synthesis from CO2 and H2. The catalysts were characterized by N2 adsorption-desorption, X-ray diffraction, field emission scanning electron microscope, temperature- programmed decomposition, and temperature-programmed reduction. The precursor from the modified method with added CO2 had malachite and hydrotalcite-like phases and was more stable than that of the sample without added CO2. After calcination, the modified catalyst had a higher surface area, larger pore volume, and smaller particle size. The modified catalyst gave a higher activity for methanol synthesis from CO2 hydrogenation in the reaction temperature range of 200–260 ºC. |
Keyword | Carbon Dioxide Assisted Aging Copper Zinc Oxide Alumina Hydrogenation Of Carbon Dioxide Methanol Synthesis |
Subject Area | 多相催化 |
Funding Organization | the National Basic Research Program of China (973 Program, 2011CB201404) |
Indexed By | SCI |
Language | 英语 |
Funding Project | 多相催化研究组 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/270 |
Collection | 羰基合成与选择氧化国家重点实验室(OSSO) |
Corresponding Author | Chou LJ(丑凌军) |
Recommended Citation GB/T 7714 | Wang DJ,Tao FR,Zhao HH,et al. Preparation of Cu/ZnO/Al2O3 Catalyst for CO2 Hydrogenation to Methanol by CO2 Assisted Aging[J]. Chin. J. Catal.,2011,32:1452-1456. |
APA | 王丹君,陶芙蓉,赵华华,宋焕玲,&丑凌军.(2011).Preparation of Cu/ZnO/Al2O3 Catalyst for CO2 Hydrogenation to Methanol by CO2 Assisted Aging.Chin. J. Catal.,32,1452-1456. |
MLA | 王丹君,et al."Preparation of Cu/ZnO/Al2O3 Catalyst for CO2 Hydrogenation to Methanol by CO2 Assisted Aging".Chin. J. Catal. 32(2011):1452-1456. |
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