| Electrochemical and photochemical characterization of novel ferrocenyl–azobenzene labeled PNA monomers for DNA detection | |
| Department | 固体润滑国家重点实验室 |
| 李进都; 陈淼; 张浩波; 刘胜 | |
| 2008 | |
| Source Publication | Inorganic Chemistry Communications
 |
| ISSN | 1387-7003 |
| Volume | 11Pages:392-395 |
| Abstract | Ferrocenyl–azobenzene carboxylic acid was synthesized and used as electrochemically and spectroscopically active marker that wasconjugated to thymine PNA monomer. Ferrocenyl–azobenzene labeled PNA monomer of thymine (Fc–Azo–T) shows highly electrochemical and photochemical activity. The detection limit of Fc–Azo–T can reach 10 6M by using differential pulsed voltammogram (DPV), and the UV–vis limit is in the order 10 7M in ethanol. Fc–Azo–T can undergo facile isomerization by photoirradiation. The results give great motivity for synthesizing ferrocenyl–azobenzene labeled PNA oligomers used as an effective electrochemical and photochemical probes. |
| Keyword | Peptide Nucleic Acid (Pna) Ferrocene Azobenzene Electrochemistry Photochemistry |
| Subject Area | 材料科学与物理化学 |
| Funding Organization | the National Nature Science Foundation of China (Grant No. 20473106);the Innovation Group Project (Grant No. 50421502);973 Project (Grant No. 2007CB607605) of the Chinese Ministry of Science and Technology |
| Indexed By | SCI |
| Language | 英语 |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/2609 |
| Collection | 固体润滑国家重点实验室（LSL） |
| Corresponding Author | 陈淼 |
| Recommended Citation GB/T 7714 | 李进都,陈淼,张浩波,等. Electrochemical and photochemical characterization of novel ferrocenyl–azobenzene labeled PNA monomers for DNA detection[J]. Inorganic Chemistry Communications,2008,11:392-395. |
| APA | 李进都,陈淼,张浩波,&刘胜.(2008).Electrochemical and photochemical characterization of novel ferrocenyl–azobenzene labeled PNA monomers for DNA detection.Inorganic Chemistry Communications,11,392-395. |
| MLA | 李进都,et al."Electrochemical and photochemical characterization of novel ferrocenyl–azobenzene labeled PNA monomers for DNA detection".Inorganic Chemistry Communications 11(2008):392-395. |
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| File Name/Size | DocType | Version | Access | License | ||
| 2008392-395.pdf（143KB） | 开放获取 | License | View Application Full Text | |||
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