| Poly(hydroethyl acrylate) grafted from ZnO nanoparticles via surface-initiated atom transfer radical polymerization | |
| Department | 固体润滑国家重点实验室 ; 先进润滑与防护材料研究发展中心 |
Liu P(刘鹏); Wang TM(王廷梅)
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| 2008 | |
| Source Publication | Current Applied Physics
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| ISSN | 1567-1739 |
| Volume | 8Pages:66-70 |
| Abstract | Poly(hydroethyl acrylate) (PHEA) was grafted from ZnO nanoparticles via the copper-mediated surface-initiated atom transfer radical polymerization (SI-ATRP) technique with the bromo-acetamide modified ZnO nanoparticles (BrA-ZnO) as macroinitiators with the catalysts of 1,10-phenanthroline and Cu(I)Br in water. Graft reaction was first order kinetic with respect to the polymerizing time in the low monomer conversion stage, this being typical for ATRP. A percentage of grafting (PG%) of 62.4% was achieved in 12 h, calculated from the elemental analysis results. The product, poly(hydroethyl acrylate) grafted ZnO nanoparticles (PHEA-ZnO) were also characterized with Fourier transform infrared spectroscopy (FT-IR), UV–vis spectroscopy, thermogravimetric analysis (TGA), X-ray photoelectron spectroscopy (XPS) and transmission electron microscopy (TEM). |
| Keyword | Surface Initiated Atom Transfer Radical Polymerization Poly(Hydroethyl Acrylate) Zno Nanoparticles |
| Subject Area | 材料科学与物理化学 |
| Funding Organization | the Natural Science Foundation of Gansu Province (3ZS041-A25-002);the Interdisciplinary Innovation Research Fund For Young Scholars, Lanzhou University (LZU200302) |
| Indexed By | SCI |
| Language | 英语 |
| Funding Project | 聚合物自润滑复合材料组 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/2598 |
| Collection | 固体润滑国家重点实验室（LSL） 中国科学院材料磨损与防护重点实验室/先进润滑与防护材料研究发展中心 |
| Corresponding Author | Liu P(刘鹏) |
| Recommended Citation GB/T 7714 | Liu P,Wang TM. Poly(hydroethyl acrylate) grafted from ZnO nanoparticles via surface-initiated atom transfer radical polymerization[J]. Current Applied Physics,2008,8:66-70. |
| APA | 刘鹏,&王廷梅.(2008).Poly(hydroethyl acrylate) grafted from ZnO nanoparticles via surface-initiated atom transfer radical polymerization.Current Applied Physics,8,66-70. |
| MLA | 刘鹏,et al."Poly(hydroethyl acrylate) grafted from ZnO nanoparticles via surface-initiated atom transfer radical polymerization".Current Applied Physics 8(2008):66-70. |
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| File Name/Size | DocType | Version | Access | License | ||
| 200866-70.pdf（289KB） | 开放获取 | License | View Application Full Text | |||
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