LICP OpenIR
Visible-light-promoted oxidative dehydrogenation of hydrazobenzenes and transfer hydrogenation of azobenzenes
DepartmentOSSO国家重点实验室
Wu LP(吴立朋)
The second department吴立朋人才团队
2019-07
Source PublicationGreen Chemistry
Issue21Pages:4189
Abstract

Azo compounds are widely used in the pharmaceutical and chemical industries. Here, we report the use of a non-metal photo-redox catalyst, Eosin Y, to synthesize azo compounds from hydrazine derivatives.
The use of visible-light with air as the oxidant makes this process sustainable and practical. Moreover, the visible-light-driven, photo-redox-catalyzed transfer hydrogenation of azobenzenes is compatible with a
series of hydrogen donors such as phenyl hydrazine and cyclic amines. Compared with traditional (thermal/transition-metal) methods, our process avoids the issue of over-reduction to aniline, which extends the applicability of photo-redox catalysis and confirms it as a useful tool for synthetic organic chemistry.

If9.405
Language英语
Funding Project前过渡金属茂基配合物催化的低碳烷烃活化转化新体系研究
compositor第一作者单位
Document Type期刊论文
Identifierhttp://ir.licp.cn/handle/362003/25757
Collection中国科学院兰州化学物理研究所
AffiliationState Key Laboratory for Oxo Synthesis and Selective Oxidation, Suzhou Research Institute of LICP, Lanzhou Institute of Chemical Physics (LICP), Chinese Academy of Sciences, Lanzhou, 730000, P. R. China.
Recommended Citation
GB/T 7714
Wu LP. Visible-light-promoted oxidative dehydrogenation of hydrazobenzenes and transfer hydrogenation of azobenzenes[J]. Green Chemistry,2019(21):4189.
APA Wu LP.(2019).Visible-light-promoted oxidative dehydrogenation of hydrazobenzenes and transfer hydrogenation of azobenzenes.Green Chemistry(21),4189.
MLA Wu LP."Visible-light-promoted oxidative dehydrogenation of hydrazobenzenes and transfer hydrogenation of azobenzenes".Green Chemistry .21(2019):4189.
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