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Electrokinetic and Colloidal Properties of Homogenized and Unhomogenized Palygorskite in the Presence of Electrolytes
Department环境材料与生态化学研究发展中心
Xu JX(徐继香); Wang AQ(王爱勤)1; Wang AQ(王爱勤)
2012
Source PublicationJournal of Chemical and Engineering Data
ISSN0021-9568
Volume57Issue:5Pages:1586-1593
AbstractA series of palygorskite samples modified with electrolytes containing LiCl, NaCl, KCl, CsCl, MgCl2, CaCl2, AlCl3, and FeCl3 were prepared with the aid of high-pressure homogenization and mechanical stirring techniques. The changes of electrokinetic and colloidal properties of modified palygorskite were investigated in detail through the measurement of the zeta potential, yield stress, and sedimentation volume. The influences of charge, concentration, and type of ions on the surface potential of palygorskite were compared. The correlation between the zeta potential and the colloidal properties of obtained palygorskite was discussed. The homogenization process could favor the adsorption of ions onto palygorskite surface and enhance the colloidal properties of suspension. It was found that the 0.05 mol·kg–1 AlCl3 and FeCl3 reversed the surface charge of palygorskite from negative to positive. The yield stress measurements demonstrated that the association capacity of rods depended on the surface potential and interparticle interactions of palygorskite. A stable suspension was obtained when palygorskite was dispersed in MgCl2 solutions and homogenized at 30 MPa.
Subject Area环境材料与生态化学
DOI10.1021/je300213u
Funding Organizationthe Science and Technology Support Project of Jiangsu Provincial Sci. & Tech. Department (No. BY2010012);Jiangsu Provincial Joint Innovation and Research Funding of Enterprises, Colleges and Institutes-Prospective Cooperative Research Project (No. BY2011194)
Indexed BySCI
If2.004
Language英语
Funding Project功能复合材料组
compositor第一作者单位
Citation statistics
Cited Times:26[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.licp.cn/handle/362003/2542
Collection环境材料与生态化学研究发展中心
Corresponding AuthorWang AQ(王爱勤)
Affiliation1.Chinese Acad Sci, Lanzhou Inst Chem Phys, Ctr Xuyi Attapulgite Appl Technol, Lanzhou 730000, Peoples R China
2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Xu JX,Wang AQ,Wang AQ. Electrokinetic and Colloidal Properties of Homogenized and Unhomogenized Palygorskite in the Presence of Electrolytes[J]. Journal of Chemical and Engineering Data,2012,57(5):1586-1593.
APA Xu JX,Wang AQ,&王爱勤.(2012).Electrokinetic and Colloidal Properties of Homogenized and Unhomogenized Palygorskite in the Presence of Electrolytes.Journal of Chemical and Engineering Data,57(5),1586-1593.
MLA Xu JX,et al."Electrokinetic and Colloidal Properties of Homogenized and Unhomogenized Palygorskite in the Presence of Electrolytes".Journal of Chemical and Engineering Data 57.5(2012):1586-1593.
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