Morphology-controlled synthesis of 3D flower-like TiO2 and the superior performance for selective catalytic reduction of NOx with NH3 | |
Department | ERC国家工程研究中心 |
Zong, Luyao1,2; Zhang GD(张国栋)1; Zhao, Jiuhu1,2; Dong F(董芳)1; Zhang, Jiyi2; Tang ZC(唐志诚)1; Tang ZC(唐志诚) | |
The second department | osso国家重点实验室 |
2018 | |
Source Publication | Chemical Engineering Journal |
ISSN | 1385-8947 |
Volume | 343Issue:0Pages:500-511 |
Abstract | Morphology of 3D TiO2 support was regulated by modulating the hydrothermal time. Notably, the increase of hydrothermal time could greatly promote the transformation of rod-like TiO2 to flower-like TiO2, while the continuous increase of hydrothermal time damaged the integrity of flower-like TiO2 and led to the appearance of large TiO2 particles. After that, a series of CeO2-WO3/TiO2 catalysts were prepared by a typical impregnation method. The catalytic performance of these CeO2-WO3/TiO2 catalysts for the selective catalytic reduction of nitrogen oxides (NH3-SCR) verified that NOx conversion was greatly related to morphological integrity of flower-like TiO2. Prominently, activity of CeO2-WO3/TiO2-8 catalyst was still excellent after introducing H2O and SO2, and thus the combined CeO2-WO3/TiO2-8 catalyst showed high catalytic activity and good resistance to H2O and SO2. Various characterizations indicated that the integrity of flower-like structure could evidently alter the surface atomic ratio of Ce3+/(Ce3+ + Ce4+) as well as acid sites. With the increase of surface atomic ratio of Ce3+/(Ce3+ + Ce4+), the SCR performance of the catalysts was obviously improved. In short, the superior catalytic performance of CeO2-WO3/TiO2 for the SCR of NOx was related to the morphology of TiO2 support, the highly dispersed active species, the valence of Ce, acid sites and lots of surface adsorbed oxygen. |
Keyword | Hydrothermal Method Flower-like Formation Process Ceo2-wo3/tio2 Ce3++++/(Ce3++++ + Ce4++++) |
Subject Area | 物理化学与绿色催化 |
DOI | 10.1016/j.cej.2018.03.035 |
Funding Organization | Science and Technology Service Network Initiative (STS) of Chinese Academy of Science (KFJSW-STS-149) ; the National Natural Science Foundation of China (21407154 ; 21507137) ; Province Natural Science Foundation of GanSu (17jRSRA317) ; Science and Technology Program of Lanzhou City (2017-4-111) |
Indexed By | SCI |
If | 6.735 |
Language | 英语 |
Funding Project | 工业催化研究组 |
compositor | 第一作者单位 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/23623 |
Collection | 精细石油化工中间体国家工程研究中心(ERC) 羰基合成与选择氧化国家重点实验室(OSSO) |
Corresponding Author | Tang ZC(唐志诚) |
Affiliation | 1.State Key Laboratory for Oxo Synthesis and Selective Oxidation, National Engineering Research Center for Fine Petrochemical Intermediates, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China 2.School of Petroleum and Chemical, Lanzhou University of Technology, Lanzhou 730050, China |
Recommended Citation GB/T 7714 | Zong, Luyao,Zhang GD,Zhao, Jiuhu,et al. Morphology-controlled synthesis of 3D flower-like TiO2 and the superior performance for selective catalytic reduction of NOx with NH3[J]. Chemical Engineering Journal,2018,343(0):500-511. |
APA | Zong, Luyao.,Zhang GD.,Zhao, Jiuhu.,Dong F.,Zhang, Jiyi.,...&Tang ZC.(2018).Morphology-controlled synthesis of 3D flower-like TiO2 and the superior performance for selective catalytic reduction of NOx with NH3.Chemical Engineering Journal,343(0),500-511. |
MLA | Zong, Luyao,et al."Morphology-controlled synthesis of 3D flower-like TiO2 and the superior performance for selective catalytic reduction of NOx with NH3".Chemical Engineering Journal 343.0(2018):500-511. |
Files in This Item: | ||||||
File Name/Size | DocType | Version | Access | License | ||
1-s2.0-S138589471830(3198KB) | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text |
Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.
Edit Comment