Adsorption properties of crosslinked carboxymethyl-chitosanresin with Pb(II) as template ions | |
Department | 环境材料与生态化学研究发展中心 |
Sun SL(孙胜玲); Wang L(王丽); Wang AQ(王爱勤); 王爱勤 aqwang@licp.cas.cn | |
2006 | |
Source Publication | Journal of Hazardous Materials B |
ISSN | 0304-3894 |
Volume | 136Pages:930-937 |
Abstract | In the current study, we attempt to find a new adsorbent material based on chitosan to improve adsorption selectivity for heavy metals, so that the crosslinkedN,O-carboxymethyl-chitosanresin with Pb(II) as templateions (crosslinked CMC template) were synthesized by using CMC adsorbed Pb(II) ionscrosslinked with glutaraldehyde. The effects on adsorption capacities such as amount of crosslinking agent, degree of substitution of CMC, pH value of the initial solution and adsorption time were investigated. The adsorption experiments demonstrated the crosslinked CMC template has high adsorption selectivity for Pb(II) ions in solution containing single metal ions or coexistence of three metals ions of Cu(II), Zn(II) and Pb(II). Furthermore, it was investigated that the crosslinked CMC template has a good reusability and stability as compared to CMC. Finally, we studied the adsorption mechanism by FTIR spectra and XPS analysis. The results reveal that the adsorption of crosslinked CMC template and CMC for Pb(II) is a chelation process. |
Keyword | Adsorption Crosslinked n Lead O-carboxymethyl-chitosan Template |
Subject Area | 胶体与界面 |
Indexed By | SCI |
Language | 英语 |
Funding Project | 功能复合材料组 |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/234 |
Collection | 环境材料与生态化学研究发展中心 |
Corresponding Author | 王爱勤 aqwang@licp.cas.cn |
Recommended Citation GB/T 7714 | Sun SL,Wang L,Wang AQ,et al. Adsorption properties of crosslinked carboxymethyl-chitosanresin with Pb(II) as template ions[J]. Journal of Hazardous Materials B,2006,136:930-937. |
APA | 孙胜玲,王丽,王爱勤,&王爱勤 aqwang@licp.cas.cn.(2006).Adsorption properties of crosslinked carboxymethyl-chitosanresin with Pb(II) as template ions.Journal of Hazardous Materials B,136,930-937. |
MLA | 孙胜玲,et al."Adsorption properties of crosslinked carboxymethyl-chitosanresin with Pb(II) as template ions".Journal of Hazardous Materials B 136(2006):930-937. |
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