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Synthesis and characterization of multifunctional poly(acrylic acid-co-acrylamide)/sodium humate superabsorbent composite
Department环境材料与生态化学研究发展中心
Zhang JP(张俊平); Li A(李安); Wang AQ(王爱勤); 王爱勤 aqwang@licp.cas.cn
2006
Source PublicationReactive and Functional Polymers
ISSN1381-5148
Volume66Pages:747-756
AbstractA novel multifunctional superabsorbent composite from acrylic acid (AA), acrylamide (AM) and sodium humate (SH), PAA–AM/SH, was prepared by aqueous solution polymerization, using N,N′-methylenebisacrylamide as a crosslinker and ammonium persulfate as an initiator. In this paper, factors influencing water absorbency of the superabsorbent composite were investigated, and then the optimal synthesis conditions were obtained as follows: the amount of crosslinker, initiator and humate, molar ratio of AA to AM, initial monomer concentration and neutralization degree of AA were 0.10 wt%, 0.40 wt%, 30 wt%, 1.2 mol mol?1, 2.02 mol L?1 and 50%, respectively. Water absorbencies for the superabsorbent composite in distilled water and in 0.9 wt% NaCl solution were investigated. Results obtained from this study indicate that the multifunctional superabsorbent composite with a humate content of 30 wt% exhibited a maximum water absorbency of 1100 g g?1 in distilled water and 55 g g?1 in 0.9 wt% NaCl solution, respectively. Thermal stability and polymerization process of the crosslinked superabsorbent composite were characterized by thermogravimetric analysis and FTIR, respectively.
KeywordSuperabsorbent Composite Water Absorbency Sodium Humate
Subject Area功能高分子
Funding Organizationthe Western Action Project of CAS (No. KGCXZ-SW-502);“863” major project of the Ministry of Science and Technology, PR China (No. 2005AA2Z4030)
Indexed BySCI
Language英语
Funding Project功能复合材料组
Citation statistics
Cited Times:71[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.licp.cn/handle/362003/228
Collection环境材料与生态化学研究发展中心
Corresponding Author王爱勤 aqwang@licp.cas.cn
Recommended Citation
GB/T 7714
Zhang JP,Li A,Wang AQ,et al. Synthesis and characterization of multifunctional poly(acrylic acid-co-acrylamide)/sodium humate superabsorbent composite[J]. Reactive and Functional Polymers,2006,66:747-756.
APA 张俊平,李安,王爱勤,&王爱勤 aqwang@licp.cas.cn.(2006).Synthesis and characterization of multifunctional poly(acrylic acid-co-acrylamide)/sodium humate superabsorbent composite.Reactive and Functional Polymers,66,747-756.
MLA 张俊平,et al."Synthesis and characterization of multifunctional poly(acrylic acid-co-acrylamide)/sodium humate superabsorbent composite".Reactive and Functional Polymers 66(2006):747-756.
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