Synthesis and characterization of multifunctional poly(acrylic acid-co-acrylamide)/sodium humate superabsorbent composite | |
Department | 环境材料与生态化学研究发展中心 |
Zhang JP(张俊平); Li A(李安); Wang AQ(王爱勤); 王爱勤 aqwang@licp.cas.cn | |
2006 | |
Source Publication | Reactive and Functional Polymers |
ISSN | 1381-5148 |
Volume | 66Pages:747-756 |
Abstract | A novel multifunctional superabsorbent composite from acrylic acid (AA), acrylamide (AM) and sodium humate (SH), PAA–AM/SH, was prepared by aqueous solution polymerization, using N,N′-methylenebisacrylamide as a crosslinker and ammonium persulfate as an initiator. In this paper, factors influencing water absorbency of the superabsorbent composite were investigated, and then the optimal synthesis conditions were obtained as follows: the amount of crosslinker, initiator and humate, molar ratio of AA to AM, initial monomer concentration and neutralization degree of AA were 0.10 wt%, 0.40 wt%, 30 wt%, 1.2 mol mol?1, 2.02 mol L?1 and 50%, respectively. Water absorbencies for the superabsorbent composite in distilled water and in 0.9 wt% NaCl solution were investigated. Results obtained from this study indicate that the multifunctional superabsorbent composite with a humate content of 30 wt% exhibited a maximum water absorbency of 1100 g g?1 in distilled water and 55 g g?1 in 0.9 wt% NaCl solution, respectively. Thermal stability and polymerization process of the crosslinked superabsorbent composite were characterized by thermogravimetric analysis and FTIR, respectively. |
Keyword | Superabsorbent Composite Water Absorbency Sodium Humate |
Subject Area | 功能高分子 |
Funding Organization | the Western Action Project of CAS (No. KGCXZ-SW-502);“863” major project of the Ministry of Science and Technology, PR China (No. 2005AA2Z4030) |
Indexed By | SCI |
Language | 英语 |
Funding Project | 功能复合材料组 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/228 |
Collection | 环境材料与生态化学研究发展中心 |
Corresponding Author | 王爱勤 aqwang@licp.cas.cn |
Recommended Citation GB/T 7714 | Zhang JP,Li A,Wang AQ,et al. Synthesis and characterization of multifunctional poly(acrylic acid-co-acrylamide)/sodium humate superabsorbent composite[J]. Reactive and Functional Polymers,2006,66:747-756. |
APA | 张俊平,李安,王爱勤,&王爱勤 aqwang@licp.cas.cn.(2006).Synthesis and characterization of multifunctional poly(acrylic acid-co-acrylamide)/sodium humate superabsorbent composite.Reactive and Functional Polymers,66,747-756. |
MLA | 张俊平,et al."Synthesis and characterization of multifunctional poly(acrylic acid-co-acrylamide)/sodium humate superabsorbent composite".Reactive and Functional Polymers 66(2006):747-756. |
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