| A new sulfonamide derivative as magnesium ion receptor: N-tosyl-2,6-diisopropyl-4-(2,3-dimethoxylbenzoylamide)aniline | |
| Department | 羰基合成与选择氧化国家重点实验室 |
Long ZR(龙泽荣); Yang PJ(杨培菊) ; Xia YN(夏娅娜); Yang ZW(杨再文); Wu B(吴彪)
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| 2009 | |
| Source Publication | Tetrahedron Letters
 |
| ISSN | 0040-4039 |
| Volume | 50Pages:1820-1824 |
| Abstract | N-Tosyl-2,6-diisopropyl-4-(2,3-dimethoxylbenzoylamide)aniline (1) has been synthesized and its metal ion (Na+, K+, Ca2+, Mg2+) coordinating properties investigated by FT-IR, ESI-MS, and 1H NMR methods. Among the tested metal ions, the overall stability constant (log K) for Mg2+ (6.89) is the highest (Na+, 5.64; K+, 5.43; Ca2+, 5.51) in 10% water/THF at 25.0 ± 0.5 C determined by UV–vis spectroscopy, indicating that 1 is a potent ionophore for Mg2+ ion. |
| Keyword | Sulfonamide N-tosyl-2 Magnesium 6-diisopropyl-4-(2 Metal Ion Binding 3- dimethoxylbenzoylamide)Aniline |
| Subject Area | 金属有机与超分子催化 |
| Funding Organization | the ‘Bairen Jihua’ program of the Chinese Academy of Sciences |
| Indexed By | SCI |
| Language | 英语 |
| Funding Project | 金属有机与超分子催化研究组 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/2289 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） |
| Corresponding Author | Wu B(吴彪) |
| Recommended Citation GB/T 7714 | Long ZR,Yang PJ,Xia YN,et al. A new sulfonamide derivative as magnesium ion receptor: N-tosyl-2,6-diisopropyl-4-(2,3-dimethoxylbenzoylamide)aniline[J]. Tetrahedron Letters,2009,50:1820-1824. |
| APA | 龙泽荣,杨培菊,夏娅娜,杨再文,&吴彪.(2009).A new sulfonamide derivative as magnesium ion receptor: N-tosyl-2,6-diisopropyl-4-(2,3-dimethoxylbenzoylamide)aniline.Tetrahedron Letters,50,1820-1824. |
| MLA | 龙泽荣,et al."A new sulfonamide derivative as magnesium ion receptor: N-tosyl-2,6-diisopropyl-4-(2,3-dimethoxylbenzoylamide)aniline".Tetrahedron Letters 50(2009):1820-1824. |
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