A Hydrogen-bonded Tubular Structure of Zinc(II) and Methyl-3-pyridylcarbamate | |
Department | 羰基合成与选择氧化国家重点实验室 |
Xia YN(夏娅娜); Li SG(李少光); Long ZR(龙泽荣); Wu B(吴彪) | |
2010 | |
Source Publication | Chinese J. Struct. Chem. |
ISSN | 0254-5861 |
Volume | 29Issue:6Pages:875-878 |
Abstract | A zinc(II) compound [ZnCl2(mpcm)2] (1, mpcm = methyl-3-pyridylcarbamate) was prepared by solvothermal reaction and characterized by elemental analysis, IR spectroscopy, TGA and single-crystal X-ray diffraction. The crystal is of monoclinic system, space group P21/n, C14H16ZnCl2N4O4, Mr = 440.58, a = 8.7893(7), b = 24.978(2), c = 9.2510(8) Å, β = 109.318(1)°, V =1916.6(3) Å3, Z = 4, θ = 1.63~25.20°, Dc = 1.527 g/cm3, μ = 1.585 mm-1, F(000) = 896, the final R = 0.0255 and wR = 0.0654 for 3080 observed reflections with I > 2σ(I). The zinc atom is four-coordinated by the pyridyl groups of two mpcm ligands and two chloride ions with a tetrahedral geometry. Two [ZnCl2(mpcm)2] subunits are held together by a pair of hydrogen bonds, forming a 32-membered macrocyclic dimer, which is further extended into a 3D tubular structure via hydrogen bonding. |
Keyword | Zinc Methyl-3-pyridylcarbamate Hydrogen-bonded Tubular Structure |
Subject Area | 金属有机功能材料 |
Funding Organization | the National Natural Science Foundation of China (No. 20872149) |
Indexed By | SCI |
Language | 英语 |
Funding Project | 金属有机与超分子催化研究组 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/2287 |
Collection | 羰基合成与选择氧化国家重点实验室(OSSO) |
Corresponding Author | Wu B(吴彪) |
Recommended Citation GB/T 7714 | Xia YN,Li SG,Long ZR,et al. A Hydrogen-bonded Tubular Structure of Zinc(II) and Methyl-3-pyridylcarbamate[J]. Chinese J. Struct. Chem.,2010,29(6):875-878. |
APA | 夏娅娜,李少光,龙泽荣,&吴彪.(2010).A Hydrogen-bonded Tubular Structure of Zinc(II) and Methyl-3-pyridylcarbamate.Chinese J. Struct. Chem.,29(6),875-878. |
MLA | 夏娅娜,et al."A Hydrogen-bonded Tubular Structure of Zinc(II) and Methyl-3-pyridylcarbamate".Chinese J. Struct. Chem. 29.6(2010):875-878. |
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