| Achieving One-Electron Oxidation of a Mononuclear Nonheme Iron(V)-Imido Complex | |
| Department | OSSO国家重点实验室 |
| Seungwoo Hong1,2; Lu, Xiaoyan1; Yong-Min Lee1; Mi Sook Seo1; Takehiro Ohta3; Takashi Ogura3; Martin Clémancey4,5,6; Pascale Maldivi7; Jean-Marc Latour4,5,6; Ritimukta Sarangi8; Wonwoo Nam1,9 | |
| 2017 | |
| Source Publication | Journal of the American Chemical Society
 |
| ISSN | 0002-7863 |
| Volume | 139Issue:41Pages:14372-14375 |
| Abstract | A mononuclear nonheme iron(V)-imido complex bearing a tetraamido macrocyclic ligand (TAML), [FeV(NTs)(TAML)]− (1), was oxidized by one-electron oxidants, affording formation of an iron(V)-imido TAML cation radical species, [FeV(NTs)(TAML+•)] (2); 2 is a diamagnetic (S = 0) complex, resulting from the antiferromagnetic coupling of the low-spin iron(V) ion (S = 1/2) with the one-electron oxidized ligand (TAML+•). 2 is a competent oxidant in C–H bond functionalization and nitrene transfer reaction, showing that the reactivity of 2 is greater than that of 1. |
| Subject Area | 物理化学与绿色催化 |
| DOI | 10.1021/jacs.7b08161 |
| Funding Organization | NRF of Korea through CRI (NRF-2012R1A3A2048842 to W.N.);GRL (NRF-2010-00353 t o W.N.);Basic Science Research Program (2017R1D1A1B03029982 to Y.M.L.);MSIP (NRF-2017R1C1B2002037 to S.H.);T.O. acknowledges the support of Grant-in-Aid for Scientific Research (No. 15H00960) by JSPS.;J.-M.L. and P.M. were supported by ANR (ANR-11-LABX-003); GENCI-IDRIS (Grant 2017-A0020807648);XAS data were measured at SSRL and R.S. was supported by NIH P41 grant (P41GM103393);DOE-BER |
| Indexed By | SCI |
| If | 13.858 |
| Language | 英语 |
| compositor | 第九作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/22738 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） |
| Corresponding Author | Pascale Maldivi; Jean-Marc Latour; Ritimukta Sarangi; Wonwoo Nam |
| Affiliation | 1.Ewha Womans Univ, Dept Chem & Nano Sci, Seoul 03760, South Korea 2.Sookmyung Womens Univ, Dept Chem, Seoul 04310, South Korea 3.Univ Hyogo, Picobiol Inst, Grad Sch Life Sci, RSC UH LP Ctr, Mikazuki, Hyogo 6795148, Japan 4.Univ Grenoble Alpes, LCBM PMB, F-38054 Grenoble, France 5.Univ Grenoble Alpes, CEA BIG CBM, F-38054 Grenoble, France 6.Univ Grenoble Alpes, CNRS, UMR 5249, F-38054 Grenoble, France 7.Univ Grenoble Alpes, CNRS, CEA, INAC,SYMMES, F-38000 Grenoble, France 8.SLAC Natl Accelerator Lab, Stanford Synchrotron Radiat Lightsource, Menlo Pk, CA 94025 USA 9.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Gansu, Peoples R China |
| Recommended Citation GB/T 7714 | Seungwoo Hong,Lu, Xiaoyan,Yong-Min Lee,et al. Achieving One-Electron Oxidation of a Mononuclear Nonheme Iron(V)-Imido Complex[J]. Journal of the American Chemical Society,2017,139(41):14372-14375. |
| APA | Seungwoo Hong.,Lu, Xiaoyan.,Yong-Min Lee.,Mi Sook Seo.,Takehiro Ohta.,...&Wonwoo Nam.(2017).Achieving One-Electron Oxidation of a Mononuclear Nonheme Iron(V)-Imido Complex.Journal of the American Chemical Society,139(41),14372-14375. |
| MLA | Seungwoo Hong,et al."Achieving One-Electron Oxidation of a Mononuclear Nonheme Iron(V)-Imido Complex".Journal of the American Chemical Society 139.41(2017):14372-14375. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| jacs.7b08161.pdf（885KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.
Edit Comment