| Oxidation-induced C-H amination leads to a new avenue to build C-N bonds | |
| Department | OSSO国家重点实验室 |
| Yi, Hong1; Tang, Zilu1; Bian, Changliang1; Chen, Hong1; Qi, Xiaotian2; Yue, Xiaoyu2; Lan, Yu2; Jyh-Fu Lee3; Lei AW(雷爱文)1,4; Lei AW(雷爱文) | |
| 2017 | |
| Source Publication | Chemical Communications
 |
| ISSN | 1359-7345 |
| Volume | 53Issue:64Pages:8984-8987 |
| Abstract | In this work, we develop an oxidation-induced C–H functionalization strategy, which not only leads to a new avenue to build C–N bonds, but also leads to different site-selectivity compared with “classic directing-groups”. The high selectivity of our new catalytic system originates from the heterogeneous electron-density distribution of the radical cation species which are induced by single electron transfer between the aromatics and oxidant-Cu(II) species. |
| Subject Area | 物理化学与绿色催化 |
| DOI | 10.1039/c7cc04955b |
| Funding Organization | the National Natural Science Foundation of China (21390400;21520102003;21272180;21302148);the Natural Science Foundation of Hubei Province (2016CFB571);The Program of Introducing Talents of Discipline to Universities of China (111 Program) |
| Indexed By | SCI |
| If | 6.319 |
| Language | 英语 |
| compositor | 第四作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/22420 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） |
| Corresponding Author | Lei AW(雷爱文) |
| Affiliation | 1.Wuhan Univ, Inst Adv Studies, Coll Chem & Mol Sci, Wuhan 430072, Hubei, Peoples R China 2.Chongqing Univ, Sch Chem & Chem Engn, Chongqing 400030, Peoples R China 3.Natl Synchrotron Radiat Res Ctr, Hsinchu 30076, Taiwan 4.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Gansu, Peoples R China |
| Recommended Citation GB/T 7714 | Yi, Hong,Tang, Zilu,Bian, Changliang,et al. Oxidation-induced C-H amination leads to a new avenue to build C-N bonds[J]. Chemical Communications,2017,53(64):8984-8987. |
| APA | Yi, Hong.,Tang, Zilu.,Bian, Changliang.,Chen, Hong.,Qi, Xiaotian.,...&雷爱文.(2017).Oxidation-induced C-H amination leads to a new avenue to build C-N bonds.Chemical Communications,53(64),8984-8987. |
| MLA | Yi, Hong,et al."Oxidation-induced C-H amination leads to a new avenue to build C-N bonds".Chemical Communications 53.64(2017):8984-8987. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| c7cc04955b.pdf（2343KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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