Synthesis of Single Atom Based Heterogeneous Platinum Catalysts: High Selectivity and Activity for Hydrosilylation Reactions | |
Department | OSSO国家重点实验室 |
Cui XJ(崔新江)1; Kathrin Junge1; Dai XC(代兴超)2; Carsten Kreyenschulte1; Marga-Martina Pohl1; Sebastian Wohlrab1; Shi F(石峰)2; Angelika Brückner1; Matthias Beller1 | |
2017 | |
Source Publication | ACS Central Science |
ISSN | 2374-7943 |
Volume | 3Issue:6Pages:580-585 |
Abstract | Catalytic hydrosilylation represents a straightforward and atom-efficient methodology for the creation of C–Si bonds. In general, the application of homogeneous platinum complexes prevails in industry and academia. Herein, we describe the first heterogeneous single atom catalysts (SACs), which are conveniently prepared by decorating alumina nanorods with platinum atoms. The resulting stable material efficiently catalyzes hydrosilylation of industrially relevant olefins with high TON (≈105). A variety of substrates is selectively hydrosilylated including compounds with sensitive reducible and other functional groups (N, B, F, Cl). The single atom based catalyst shows significantly higher activity compared to related Pt nanoparticles. |
Subject Area | 物理化学与绿色催化 |
DOI | 10.1021/acscentsci.7b00105 |
Funding Organization | the state of Mecklenburg-Vorpommern |
Indexed By | SCI |
If | 7.481 |
Language | 英语 |
Funding Project | 纳米催化研究组 |
compositor | 第二作者单位 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/22102 |
Collection | 羰基合成与选择氧化国家重点实验室(OSSO) |
Corresponding Author | Matthias Beller |
Affiliation | 1.Univ Rostock, Leibniz Inst Katalyse eV, Albert Einstein Str 29a, D-18059 Rostock, Germany 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, 18 Tianshui Middle Rd, Lanzhou 730000, Peoples R China |
Recommended Citation GB/T 7714 | Cui XJ,Kathrin Junge,Dai XC,et al. Synthesis of Single Atom Based Heterogeneous Platinum Catalysts: High Selectivity and Activity for Hydrosilylation Reactions[J]. ACS Central Science,2017,3(6):580-585. |
APA | Cui XJ.,Kathrin Junge.,Dai XC.,Carsten Kreyenschulte.,Marga-Martina Pohl.,...&Matthias Beller.(2017).Synthesis of Single Atom Based Heterogeneous Platinum Catalysts: High Selectivity and Activity for Hydrosilylation Reactions.ACS Central Science,3(6),580-585. |
MLA | Cui XJ,et al."Synthesis of Single Atom Based Heterogeneous Platinum Catalysts: High Selectivity and Activity for Hydrosilylation Reactions".ACS Central Science 3.6(2017):580-585. |
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acscentsci.7b00105.p(2540KB) | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text |
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