| Selective catalytrc formic acid decomposition for hydrogen generation in ionic liquids | |
| Department | 绿色化学研究发展中心 |
Li XL(李雪礼); Shi F(石峰) ; Ma XY(马祥元); Lu LJ(卢六斤); Deng YQ(邓友全)
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| 2010 | |
| Source Publication | Journal of Fuel Chemistry and Technology
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| ISSN | 0253-2409 |
| Volume | 38Issue:5Pages:1-10 |
| Abstract | Effect of ionic liquids (ILs) as media on the decomposition of formic acid in the presence of organic amine was investigated and the activity was dramatically promoted by the addition of ILs, especially for BMImCl. based on this and in order to avoid volatile organic amine, a series of amine-functionalized ILs were further designed and prepared as both reaction media and co-catalyst for homogeneous decomposition of formic acid. Among them investigated, i-Pr2NEMImCl-HCOONa system exhibited high activity (TOF＞600 mol/mol/h). This efficient and green method to produce hydrogen by formic acid decomposition has practical potentiality. |
| Keyword | Formic Acid Decomposition Hydrogen Ionic Liquids Green Chemistry 甲酸 分解 氢 离子液体 绿色化学 |
| Subject Area | 物理化学 |
| Funding Organization | 国家自然科基金No. 20533080 |
| Indexed By | EI ; CSCD |
| Language | 英语 |
| Funding Project | 绿色催化课题 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/2209 |
| Collection | 绿色化学研究发展中心 |
| Corresponding Author | Shi F(石峰); Deng YQ(邓友全) |
| Recommended Citation GB/T 7714 | Li XL,Shi F,Ma XY,et al. Selective catalytrc formic acid decomposition for hydrogen generation in ionic liquids[J]. Journal of Fuel Chemistry and Technology,2010,38(5):1-10. |
| APA | 李雪礼,石峰,马祥元,卢六斤,&邓友全.(2010).Selective catalytrc formic acid decomposition for hydrogen generation in ionic liquids.Journal of Fuel Chemistry and Technology,38(5),1-10. |
| MLA | 李雪礼,et al."Selective catalytrc formic acid decomposition for hydrogen generation in ionic liquids".Journal of Fuel Chemistry and Technology 38.5(2010):1-10. |
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| 燃料化学学报-2010,38,1-10.（0KB） | 开放获取 | License | View Application Full Text | |||
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