| Metal-free radical oxidative alkoxycarbonylation and imidation of alkanes | |
| Department | OSSO国家重点实验室 |
| Lu, Lijun1; Cheng, Danyang1; Zhan, Yuanfeng1; Shi, Renyi1; Chiang, Chien-Wei1; Lei AW(雷爱文)1,2; Lei AW(雷爱文) | |
| 2017 | |
| Source Publication | Chemical Communications
 |
| ISSN | 1359-7345 |
| Volume | 53Issue:51Pages:6852-6855 |
| Abstract | A metal-free radical oxidative carbonylation of alkanes is demonstrated, yielding esters and imides by means of di-tert-butylperoxide as an oxidant. Various alkanes, alcohols and amides were compatible in this system generating the desired carbonyl products in up to 86% yields. We proposed a plausible radical cross-coupling process based on the preliminary mechanistic studies. |
| Subject Area | 物理化学与绿色催化 |
| DOI | 10.1039/c7cc03671j |
| Funding Organization | the National Natural Science Foundation of China (21390402;21520102003);the Ministry of Science and Technology of China (2012YQ120060);the Fundamental Research Funds for the Central Universities and the Program of Introducing Talents of Discipline to Universities of China (111 Program) |
| Indexed By | SCI |
| If | 6.319 |
| Language | 英语 |
| compositor | 第二作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/22043 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） |
| Corresponding Author | Lei AW(雷爱文) |
| Affiliation | 1.Wuhan Univ, Inst Adv Studies, Coll Chem & Mol Sci, Wuhan 430072, Peoples R China 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China |
| Recommended Citation GB/T 7714 | Lu, Lijun,Cheng, Danyang,Zhan, Yuanfeng,et al. Metal-free radical oxidative alkoxycarbonylation and imidation of alkanes[J]. Chemical Communications,2017,53(51):6852-6855. |
| APA | Lu, Lijun.,Cheng, Danyang.,Zhan, Yuanfeng.,Shi, Renyi.,Chiang, Chien-Wei.,...&雷爱文.(2017).Metal-free radical oxidative alkoxycarbonylation and imidation of alkanes.Chemical Communications,53(51),6852-6855. |
| MLA | Lu, Lijun,et al."Metal-free radical oxidative alkoxycarbonylation and imidation of alkanes".Chemical Communications 53.51(2017):6852-6855. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| c7cc03671j.pdf（1428KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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