Photoluminescent Honeycomb Structures from Polyoxometalates and an Imidazolium-Based Ionic Liquid Bearing a pi-Conjugated Moiety and a Branched Aliphatic Chain | |
Department | 清洁能源化学与材料实验室 |
Zhang, Geping1; Zhu, Hongxia1; Chen, Mengjun1; Li HG(李洪光)2; Yuan, Ye3; Ma, Tiantai3; Hao JC(郝京诚)1; Li HG(李洪光); Hao JC(郝京诚) | |
The second department | 固体润滑国家重点实验室 |
2017 | |
Source Publication | Chemistry - A European Journal |
ISSN | 0947-6539 |
Volume | 23Issue:30Pages:7278-7286 |
Abstract | Honeycomb-structured films represent an intriguing class of two-dimensional porous materials. Specifically, polyoxometalate (POM) macroanions can be introduced into these films by complexing with oppositely charged, doubletailed surfactants. Here highly-ordered honeycomb structures are reported that can be constructed by the complexes between POMs and a room temperature ionic liquid (IL1) having an imidazolium moiety in the middle and a naphthyl unit and a branched aliphatic chain at the ends. The complexes can be produced through phase transfer between an aqueous solution of POMs (typically {Mo72Fe30}) and a CS2 (or chloroform) solution of IL1. Based on the intrinsic properties of {Mo72Fe30} and the functional groups of the IL1, the honeycomb structures show multiple functions with bright photoluminescence and rich electrochemical properties. This work shows that by simply engineering the organic ligands involved in the POM-based inorganic-organic complexes, supramolecular structures with improved properties and wide applications can be obtained. |
Keyword | Honeycomb Structure Ionic Liquid Phase Transfer Photoluminescence Polyoxometalates |
Subject Area | 材料科学与物理化学 |
DOI | 10.1002/chem.201605651 |
Funding Organization | the National Natural Science Foundation of China (Nos. 21420102006;61474124);the Hundred Talents Program of Chinese Academy of Sciences (Y20245YBR1) |
Indexed By | SCI |
If | 5.317 |
Language | 英语 |
Funding Project | 柔性有机太阳能电池研究组 |
compositor | 第二作者单位 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/21970 |
Collection | 清洁能源化学与材料实验室 固体润滑国家重点实验室(LSL) |
Corresponding Author | Li HG(李洪光); Hao JC(郝京诚) |
Affiliation | 1.Key Laboratory of Colloid and Interface Chemistry & Key Laboratory of Special Aggregated Materials Ministry of Education, Shandong University Jinan, 250100 (P.R.China) 2.State Key Laboratory of Solid Lubrication Laboratory of Clean Energy Chemistry and Materials Lanzhou Institute of Chemical Physics Chinese Academy of Sciences Lanzhou, 730000 (P.R.China) 3.Taishan College, Shandong University Jinan, 250100 (P.R.China) |
Recommended Citation GB/T 7714 | Zhang, Geping,Zhu, Hongxia,Chen, Mengjun,et al. Photoluminescent Honeycomb Structures from Polyoxometalates and an Imidazolium-Based Ionic Liquid Bearing a pi-Conjugated Moiety and a Branched Aliphatic Chain[J]. Chemistry - A European Journal,2017,23(30):7278-7286. |
APA | Zhang, Geping.,Zhu, Hongxia.,Chen, Mengjun.,Li HG.,Yuan, Ye.,...&郝京诚.(2017).Photoluminescent Honeycomb Structures from Polyoxometalates and an Imidazolium-Based Ionic Liquid Bearing a pi-Conjugated Moiety and a Branched Aliphatic Chain.Chemistry - A European Journal,23(30),7278-7286. |
MLA | Zhang, Geping,et al."Photoluminescent Honeycomb Structures from Polyoxometalates and an Imidazolium-Based Ionic Liquid Bearing a pi-Conjugated Moiety and a Branched Aliphatic Chain".Chemistry - A European Journal 23.30(2017):7278-7286. |
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