Facile one-step precursor-to-aerogel synthesis of silica-doped alumina aerogels with high specific surface area at elevated temperatures | |
Department | 先进润滑与防护材料研究发展中心 |
Yang JF(杨景锋)1,2; Wang QH(王齐华)1; Wang TM(王廷梅)1; Liang YM(梁永民)3; Wang QH(王齐华) | |
The second department | 固体润滑国家重点实验室 |
2016 | |
Source Publication | Journal of Porous Materials |
ISSN | 1380-2224 |
Volume | 24Issue:4Pages:889-897 |
Abstract | Silica-doped alumina aerogels offer the potential alternative to the applications as thermal insulators, catalysis, or catalytic support at elevated temperatures. However, the production process of silica-doped alumina aerogels was complicated and time-consuming. We developed a one-step precursor-to-aerogel method of silica-doped alumina aerogels with high specific surface area and thermal stability. Compared to conventional methods, the developed method reduced time and solvent waste of alumina-based aerogels production. Here, we investigated the alumina aerogels doped with silica to stabilize γ-phase at higher temperatures. XRD, FTIR, TEM, TG-DSC, and BET analysis results showed that silica stabilized the γ-Al2O3 at 1200 °C. The stabilization mechanism analysis showed that silica addition could significantly hinder the contact among alumina particles and the formation of necks in the sintering process, thereby retarding the transition of γ–θ phase and maintaining the high specific surface area at elevated temperatures. Silica and alumina particles formed mullite at 1200 °C, which could suppress α-phase transformation. In addition, silica-doped alumina aerogels exhibited the high specific surface area of 311 m2/g at 1000 °C and 146 m2/g at 1200 °C when the silica content was in the range of 10.6–13.1 wt%. |
Keyword | Alumina Aerogel Silica-doped Alumina Aerogel Rapid Supercritical Drying Process Specific Surface Area Thermal Stability |
Subject Area | 材料科学与物理化学 |
DOI | 10.1007/s10934-016-0328-3 |
Funding Organization | the National Basic Research Program of China (973 Program, Grant No. 2015CB057502) |
Indexed By | SCI |
If | 1.624 |
Language | 英语 |
Funding Project | 聚合物自润滑复合材料组 |
compositor | 第一作者单位 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/21817 |
Collection | 中国科学院材料磨损与防护重点实验室/先进润滑与防护材料研究发展中心 固体润滑国家重点实验室(LSL) |
Corresponding Author | Wang QH(王齐华) |
Affiliation | 1.State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou, People’s Republic of China 2.University of Chinese Academy of Sciences, Beijing, People’s Republic of China 3.State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou, People’s Republic of China |
Recommended Citation GB/T 7714 | Yang JF,Wang QH,Wang TM,et al. Facile one-step precursor-to-aerogel synthesis of silica-doped alumina aerogels with high specific surface area at elevated temperatures[J]. Journal of Porous Materials,2016,24(4):889-897. |
APA | Yang JF,Wang QH,Wang TM,Liang YM,&王齐华.(2016).Facile one-step precursor-to-aerogel synthesis of silica-doped alumina aerogels with high specific surface area at elevated temperatures.Journal of Porous Materials,24(4),889-897. |
MLA | Yang JF,et al."Facile one-step precursor-to-aerogel synthesis of silica-doped alumina aerogels with high specific surface area at elevated temperatures".Journal of Porous Materials 24.4(2016):889-897. |
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