| Tandem Spirocyclopropanation/Rearrangement Reaction of Vinyl p-Quinone Methides with Sulfonium Salts: Synthesis of Spirocyclopentenyl p-Dienones | |
| Department | OSSO国家重点实验室 |
| Zhang, Xiang-Zhi1; Deng, Yu-Hua1,3; Gan, Kang-Ji1; Yan, Xu1; Yu, Ke-Yin1; Wang, Fang-Xin1; Fan, Chun-An1,2 | |
| 2017 | |
| Source Publication | Organic Letters
 |
| ISSN | 1523-7060 |
| Volume | 19Issue:7Pages:1752-1755 |
| Abstract | A novel base-mediated tandem spirocyclopropanation/rearrangement reaction of vinyl p-quinone methides (p-VQMs) with sulfonium salts is described. The unprecedented reactivity of p-VQMs was explored for the first time in the spiroannulation cascade, providing a stereoselective approach to the construction of synthetically interesting, densely functionalized spirocyclopentenyl p-dienones. |
| Subject Area | 物理化学与绿色催化 |
| DOI | 10.1021/acs.orglett.7b00516 |
| Funding Organization | NSFC (21572083;21322201;21290180);FRFCU (lzujbky-2015-48;lzujbky-2016-ct02;lzujbky-2016-ct07);PCSIRT (IRT_15R28);the 111 Project of MOE (111-2-17);the Chang Jiang Scholars Program (C.-A.F.) |
| Indexed By | SCI |
| If | 6.579 |
| Language | 英语 |
| compositor | 第三作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/21787 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） |
| Corresponding Author | Fan, Chun-An |
| Affiliation | 1.Lanzhou Univ, Coll Chem & Chem Engn, State Key Lab Appl Organ Chem, 222 Tianshui Nanlu, Lanzhou 730000, Peoples R China 2.Collaborat Innovat Ctr Chem Sci & Engn Tianjin, Tianjin 300071, Peoples R China 3.Chinese Acad Sci, State Key Lab Oxo Synth & Select Oxidat, Lanzhou Inst Chem Phys, Lanzhou 730000, Peoples R China |
| Recommended Citation GB/T 7714 | Zhang, Xiang-Zhi,Deng, Yu-Hua,Gan, Kang-Ji,et al. Tandem Spirocyclopropanation/Rearrangement Reaction of Vinyl p-Quinone Methides with Sulfonium Salts: Synthesis of Spirocyclopentenyl p-Dienones[J]. Organic Letters,2017,19(7):1752-1755. |
| APA | Zhang, Xiang-Zhi.,Deng, Yu-Hua.,Gan, Kang-Ji.,Yan, Xu.,Yu, Ke-Yin.,...&Fan, Chun-An.(2017).Tandem Spirocyclopropanation/Rearrangement Reaction of Vinyl p-Quinone Methides with Sulfonium Salts: Synthesis of Spirocyclopentenyl p-Dienones.Organic Letters,19(7),1752-1755. |
| MLA | Zhang, Xiang-Zhi,et al."Tandem Spirocyclopropanation/Rearrangement Reaction of Vinyl p-Quinone Methides with Sulfonium Salts: Synthesis of Spirocyclopentenyl p-Dienones".Organic Letters 19.7(2017):1752-1755. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| acs.orglett.7b00516.（1100KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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