Room-temperature processible TiO2 electron selective layers with controllable crystallinity for high efficiency perovskite photovoltaics | |
Department | 固体润滑国家重点实验室 |
Huang, Aibin1,2; Zhu, Jingting1,2; Zheng JY(郑建云)3; Yu, Yu1,2; Liu, Yan1; Yang, Songwang4; Bao, Shanhu1; Lei, Lei1; Jin, Ping1,5 | |
2017 | |
Source Publication | Solar Energy Materials and Solar Cells |
ISSN | 0927-0248 |
Volume | 163Pages:15-22 |
Abstract | As a remarkable wide band-gap n-type semiconductor, TiO2 has been widely used as electron selective layer in photovoltaic devices. In this work, TiO2 films with different crystallinity were deposited on FTO glass by DC magnetron sputtering at room temperature. The crystallinity of these films were controlled by precisely adjusting the sputtering power and work pressure. Taking advantages of high visible light transmittance, reduced transport resistance and effective TiO2/perovskite interface with fast electron extraction and carrier separation, high efficiency perovskite solar cells (PSCs) were assembled. The optimum crystallinity of TiO2 compact layer for PSC was defined as 26.3%. Short-circuit current density and fill factor were notably enhanced and power conversion efficiency of the device was improved to 15.76% compared with PSCs based on amorphous (13.3%) and fully crystallized TiO2 (12.9%). This research shaded light on the choice of inorganic carrier transport layers in photovoltaic devices. |
Keyword | Magnetron Sputtering Tio2 Electron Transport Layer Crystallinity Engineering Perovskite Solar Cells |
Subject Area | 材料科学与物理化学 |
DOI | 10.1016/j.solmat.2017.01.006 |
Funding Organization | the high-tech project of MOST (No.: 2014AA032802);the Key Research Program of the Chinese Academy of Sciences (No.: KFZD-SW-403);the Science and Technology Commission of Shanghai Municipality (STCSM, No.: 13NM1402200);the Shanghai Municipal Natural Science Foundation (Grant No. 16ZR144100) |
Indexed By | SCI |
If | 4.784 |
Language | 英语 |
compositor | 第三作者单位 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/21619 |
Collection | 固体润滑国家重点实验室(LSL) |
Corresponding Author | Lei, Lei; Jin, Ping |
Affiliation | 1.Chinese Acad Sci, Shanghai Inst Ceram, State Key Lab High Performance Ceram & Superfine, Dingxi 1295, Shanghai 200050, Peoples R China 2.Univ Chinese Acad Sci, Yuquan 19, Beijing 100049, Peoples R China 3.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Lanzhou 730000, Peoples R China 4.Chinese Acad Sci, Shanghai Inst Ceram, Key Lab Mat Energy Convers, Heshuo 588, Shanghai 201899, Peoples R China 5.Natl Inst Adv Ind Sci & Technol, Nagoya, Aichi 4638560, Japan |
Recommended Citation GB/T 7714 | Huang, Aibin,Zhu, Jingting,Zheng JY,et al. Room-temperature processible TiO2 electron selective layers with controllable crystallinity for high efficiency perovskite photovoltaics[J]. Solar Energy Materials and Solar Cells,2017,163:15-22. |
APA | Huang, Aibin.,Zhu, Jingting.,Zheng JY.,Yu, Yu.,Liu, Yan.,...&Jin, Ping.(2017).Room-temperature processible TiO2 electron selective layers with controllable crystallinity for high efficiency perovskite photovoltaics.Solar Energy Materials and Solar Cells,163,15-22. |
MLA | Huang, Aibin,et al."Room-temperature processible TiO2 electron selective layers with controllable crystallinity for high efficiency perovskite photovoltaics".Solar Energy Materials and Solar Cells 163(2017):15-22. |
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