Recent Advances in the Enantioselective Oxidative -C-H Functionalization of Amines | |
Department | OSSO国家重点实验室 |
Cheng, Ming-Xing1; Yang SD(杨尚东)1,2; Yang SD(杨尚东) | |
2017 | |
Source Publication | SYNLETT |
ISSN | 0936-5214 |
Volume | 28Issue:2Pages:159-174 |
Abstract | Cross-dehydrogenative coupling (CDC) has emerged as a powerful synthetic method for the straightforward and efficient construction of C–C and C–heteroatom bonds. In particular, asymmetric versions of this reaction are highly desirable, since they would provide a simple approach to complex molecules from simple materials without any prefunctionalization of substrates. In recent years, great achievements have been made in this area, and many powerful approaches have been developed for this transformation with high enantioselectivity. In this account, we summarize recent advances in the enantioselective oxidative α-C(sp3)–H bond functionalization of amines according to the catalytic reaction systems. Moreover, the catalytic mechanisms of the asymmetric oxidative reactions are also discussed. |
Keyword | Cross-dehydrogenative Coupling Amines Asymmetric Synthesis Oxidative C-h Functionalization |
Subject Area | 物理化学与绿色催化 |
DOI | 10.1055/s-0036-1588342 |
Funding Organization | the NSFC (No. 21272100;21472076;21532001);Program for the Fundamental Research Funds for the Central Universities (lzujbky-2014-239) |
Indexed By | SCI |
If | 2.151 |
Language | 英语 |
compositor | 第二作者单位 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/21479 |
Collection | 羰基合成与选择氧化国家重点实验室(OSSO) |
Corresponding Author | Yang SD(杨尚东) |
Affiliation | 1.Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China |
Recommended Citation GB/T 7714 | Cheng, Ming-Xing,Yang SD,Yang SD. Recent Advances in the Enantioselective Oxidative -C-H Functionalization of Amines[J]. SYNLETT,2017,28(2):159-174. |
APA | Cheng, Ming-Xing,Yang SD,&杨尚东.(2017).Recent Advances in the Enantioselective Oxidative -C-H Functionalization of Amines.SYNLETT,28(2),159-174. |
MLA | Cheng, Ming-Xing,et al."Recent Advances in the Enantioselective Oxidative -C-H Functionalization of Amines".SYNLETT 28.2(2017):159-174. |
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Synlett2017v28n2p159(1097KB) | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text |
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