| Tetraethylammonium iodide catalyzed synthesis of diaryl ketones via the merger of cleavage of C-C double bonds and recombination of aromatic groups | |
| Department | OSSO国家重点实验室 |
Ceng XH(曾祥华)1,2; Xu DQ(徐大乾)1; Miao CX(苗成霞)1 ; Xia CG(夏春谷)1; Sun W(孙伟)1; Sun W(孙伟)
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| 2014 | |
| Source Publication | RSC Advances
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| ISSN | 2046-2069 |
| Volume | 4Issue:87Pages:46494-46497 |
| Abstract | An efficient method for synthesizing diaryl ketones via merging of oxidative cleavage of C–C double bonds and recombination of aromatic groups is developed with Et4NI (2.5 mol%) as the catalyst and NaIO4 as the oxidant. The control experiments provide valuable mechanistic insights into the formation of diaryl ketones, and suggest that NaIO4 serves as an epoxidation and nucleophilic deformylation reagent. |
| Subject Area | 物理化学与绿色催化 |
| DOI | 10.1039/c4ra08764j |
| Funding Organization | the Chinese Academy of Sciences;the National Natural Science Foundation of China (21133011;21103207) |
| Indexed By | SCI |
| If | 3.840 |
| Language | 英语 |
| Funding Project | 生物与仿生催化课题组;均相催化课题组 |
| compositor | 第一作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/21324 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） |
| Corresponding Author | Sun W(孙伟) |
| Affiliation | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China 2.Jiaxing Univ, Coll Biol Chem Sci & Engn, Jiaxing 314001, Peoples R China |
| Recommended Citation GB/T 7714 | Ceng XH,Xu DQ,Miao CX,et al. Tetraethylammonium iodide catalyzed synthesis of diaryl ketones via the merger of cleavage of C-C double bonds and recombination of aromatic groups[J]. RSC Advances,2014,4(87):46494-46497. |
| APA | Ceng XH,Xu DQ,Miao CX,Xia CG,Sun W,&孙伟.(2014).Tetraethylammonium iodide catalyzed synthesis of diaryl ketones via the merger of cleavage of C-C double bonds and recombination of aromatic groups.RSC Advances,4(87),46494-46497. |
| MLA | Ceng XH,et al."Tetraethylammonium iodide catalyzed synthesis of diaryl ketones via the merger of cleavage of C-C double bonds and recombination of aromatic groups".RSC Advances 4.87(2014):46494-46497. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| c4ra08764j.pdf（246KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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