A stable and practical nickel catalyst for the hydrogenolysis of C-O bonds | |
Department | OSSO国家重点实验室 |
Cui XJ(崔新江)1; Yuan HK(袁航空)2; Kathrin Junge1; Christoph Topf1; Matthias Beller1; Shi F(石峰)2; Shi F(石峰) | |
2017 | |
Source Publication | Green Chemistry |
ISSN | 1463-9262 |
Volume | 19Issue:1Pages:305-310 |
Abstract | The selective hydrogenolysis of C–O bonds constitutes a key step for the valorization of biomass including lignin fragments. Moreover, this defunctionalization process offers the possibility of producing interesting organic building blocks in a straightforward manner from oxygenated compounds. Herein, we demonstrate the reductive hydrogenolysis of a wide variety of ethers including diaryl, aryl–alkyl and aryl–benzyl derivatives catalyzed by a stable heterogeneous NiAlOx catalyst in the presence of a Lewis acid (LA). The special feature of this catalyst system is the formation of substituted cyclohexanols from the corresponding aryl ether. |
Subject Area | 物理化学与绿色催化 |
DOI | 10.1039/c6gc01955b |
Indexed By | SCI |
If | 9.125 |
Language | 英语 |
Funding Project | 纳米催化课题组 |
compositor | 第二作者单位 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/21292 |
Collection | 羰基合成与选择氧化国家重点实验室(OSSO) |
Corresponding Author | Matthias Beller; Shi F(石峰) |
Affiliation | 1.Leibniz Inst Katalyse eV, Albert Einstein Str 29a, D-18059 Rostock, Germany 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, Ctr Green Chem & Catalysis, State Key Lab Oxo Synth & Select Oxidat, 18 Tianshui Middle Rd, Lanzhou 730000, Peoples R China |
Recommended Citation GB/T 7714 | Cui XJ,Yuan HK,Kathrin Junge,et al. A stable and practical nickel catalyst for the hydrogenolysis of C-O bonds[J]. Green Chemistry,2017,19(1):305-310. |
APA | Cui XJ.,Yuan HK.,Kathrin Junge.,Christoph Topf.,Matthias Beller.,...&石峰.(2017).A stable and practical nickel catalyst for the hydrogenolysis of C-O bonds.Green Chemistry,19(1),305-310. |
MLA | Cui XJ,et al."A stable and practical nickel catalyst for the hydrogenolysis of C-O bonds".Green Chemistry 19.1(2017):305-310. |
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c6gc01955b.pdf(900KB) | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text |
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