Supramolecular Assembly and Nanostructures of a Series of Luminol Derivatives with Aromatic/Alkyl Substituted Groups in Langmuir-Blodgett Films | |
Department | 固体润滑国家重点实验室 |
Jiao TF(焦体峰)1,2; Xing, Yuanyuan1; Zhang, Qingrui1; Zhang, Li3; Liu, Minghua3; Zhou JX(周靖欣)1; Gao FM(高发明)1; Jiao TF(焦体峰) | |
2014 | |
Source Publication | Journal of Nanoscience and Nanotechnology |
ISSN | 1533-4880 |
Volume | 14Issue:6Pages:4400-4404 |
Abstract | A series of functional luminol derivatives with aromatic and alkyl substituted groups has been designed and synthesized from the reaction of the corresponding chloride precursors with luminol. These compounds can be spread on water surface to form stable Langmuir films at the air-water interface. It has been found that UV and IR spectra confirmed the characteristic aromatic segment, imide group, and aromatic/alkyl substituted groups. In addition, for the interfacial assembly process of compounds with alkyl substituted groups, there are obvious spectral changes for the alkyl chains. AFM results indicated that various different aggregated domains may be fabricated in the transferred LB films. For all cases, the substituted groups in molecular structures have an important effect in regulating the aggregation mode and spectral changes in organized molecular films. The present results showed that the modified luminol derivatives may have potential application in functional material fields such as ECL sensor, which may give some insight to study the relationship between the molecular structures and supramolecular aggregation of amphiphiles in organized molecular films. |
Keyword | Supramolecular Assembly Langmuir-blodgett Film Luminol Derivative Substituted Group Electrochemiluminescence Nanostructure |
Subject Area | 材料科学与物理化学 |
DOI | 10.1166/jnn.2014.8056 |
Funding Organization | the National Natural Science Foundation of China (Grant Nos. 20903078;21207112);the Natural Science Foundation of Hebei Peovince (Grant Nos. B2012203060;B2013203108);the China Postdoctoral Science Foundation (Grant Nos. 2011M500540;2012M510770);the Support Program for Hundred Excellent Innovation Talents from Universities and Colleges of Hebei Province (Grant No. CPRC020);the Science Foundation for the Excellent Youth Scholars from Universitise and Colleges of Hebei Province (Grant No. Y2011113);the Scientific Research Foundation for Returned Oversea Chinese Scholars of Hebei Province (Grant No. 2011052);the Open Foundation of State Key Laboratory of Solid Lubrication of Chinese Academy of Sciences (Grant No. 1002) |
Indexed By | SCI |
If | 1.556 |
Language | 英语 |
compositor | 第二作者单位 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/21230 |
Collection | 固体润滑国家重点实验室(LSL) |
Corresponding Author | Zhang, Qingrui; Jiao TF(焦体峰) |
Affiliation | 1.Yanshan Univ, Sch Environm & Chem Engn, Hebei Key Lab Appl Chem, Qinhuangdao 066004, Peoples R China 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Lanzhou 730000, Peoples R China 3.Chinese Acad Sci, CAS Key Lab Colloid & Interface Sci, Beijing Natl Lab Mol Sci, Inst Chem, Beijing 100190, Peoples R China |
Recommended Citation GB/T 7714 | Jiao TF,Xing, Yuanyuan,Zhang, Qingrui,et al. Supramolecular Assembly and Nanostructures of a Series of Luminol Derivatives with Aromatic/Alkyl Substituted Groups in Langmuir-Blodgett Films[J]. Journal of Nanoscience and Nanotechnology,2014,14(6):4400-4404. |
APA | Jiao TF.,Xing, Yuanyuan.,Zhang, Qingrui.,Zhang, Li.,Liu, Minghua.,...&焦体峰.(2014).Supramolecular Assembly and Nanostructures of a Series of Luminol Derivatives with Aromatic/Alkyl Substituted Groups in Langmuir-Blodgett Films.Journal of Nanoscience and Nanotechnology,14(6),4400-4404. |
MLA | Jiao TF,et al."Supramolecular Assembly and Nanostructures of a Series of Luminol Derivatives with Aromatic/Alkyl Substituted Groups in Langmuir-Blodgett Films".Journal of Nanoscience and Nanotechnology 14.6(2014):4400-4404. |
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