| Silver-catalyzed nucleophilic substitution of aminals with ethyl diazoacetate: a new pathway to beta-amino-alpha-diazoesters | |
| Department | OSSO国家重点实验室 |
Li JW(李加文)1,3; Qin GP(秦贵平)1,3; Huang HM(黄汉民)1,2 ; Huang HM(黄汉民)
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| 2016 | |
| Source Publication | Organic and Biomolecular Chemistry
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| ISSN | 1477-0520 |
| Volume | 14Issue:45Pages:10572-10575 |
| Abstract | A novel silver-catalyzed nucleophilic substitution of aminals with ethyl diazoacetate producing β-amino-α-diazoesters has been developed. A series of aminals with different amino moieties and substituents were successfully incorporated in this reaction, which delivered a wide range of β-amino-α-diazocarbonyl compounds in the presence of a lower catalyst loading in 2 hours. |
| Subject Area | 物理化学与绿色催化 |
| DOI | 10.1039/c6ob02136k |
| Funding Organization | the CAS Interdisciplinary Innovation Team;the National Natural Science Foundation of China (21133011;21672199) |
| Indexed By | SCI |
| If | 3.564 |
| Language | 英语 |
| compositor | 第一作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/21203 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） |
| Corresponding Author | Huang HM(黄汉民) |
| Affiliation | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China 2.Univ Sci & Technol China, Dept Chem, Hefei 230026, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| Recommended Citation GB/T 7714 | Li JW,Qin GP,Huang HM,et al. Silver-catalyzed nucleophilic substitution of aminals with ethyl diazoacetate: a new pathway to beta-amino-alpha-diazoesters[J]. Organic and Biomolecular Chemistry,2016,14(45):10572-10575. |
| APA | Li JW,Qin GP,Huang HM,&黄汉民.(2016).Silver-catalyzed nucleophilic substitution of aminals with ethyl diazoacetate: a new pathway to beta-amino-alpha-diazoesters.Organic and Biomolecular Chemistry,14(45),10572-10575. |
| MLA | Li JW,et al."Silver-catalyzed nucleophilic substitution of aminals with ethyl diazoacetate: a new pathway to beta-amino-alpha-diazoesters".Organic and Biomolecular Chemistry 14.45(2016):10572-10575. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| c6ob02136k.pdf（897KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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