A replication strategy for complex micro/nanostructures with superhydrophobicity and superoleophobicity and high contrast adhesion | |
Department | 固体润滑国家重点实验室 ; 先进润滑与防护材料研究发展中心 |
Liu XJ(刘新杰); Wu WC(吴伟词); Wang XL(王晓龙); Luo ZZ(罗莊竹); Liang YM(梁永民); Zhou F(周峰) | |
2009 | |
Source Publication | Soft Matter |
ISSN | 1744-683X |
Volume | 5Pages:3097-3105 |
Abstract | The present work reports a replication approach to imprint complex micro/nanostructures into polymeric coatings and materials, such as silicone elastomers, polyurethane, ultra-high-molecular- weight polyethylene and polytetrafluoroethylene etc., with applications in engineering. Al and Al2O3 molds with terraced micro/nanostructures were produced using an industrially compatible anodization method. To assist replication, the molds were coated with a water-soluble polymer layer as the sacrificial layer, to reduce the adhesion between replica and mold. Polymeric replicas with complex terraced structures were successfully obtained, which were otherwise impossible to achieve with conventional perfluorinated molds. The as-prepared replicas all exhibited superhydrophobicity without further modification with low-surface-energy coatings. Interestingly, residual hydrophilic sacrificial layer resulted in high water-adhesion without losing superhydrophobicity; these surfaces turned extremely slippery after removal of the residual sacrificial layer. A molecular mechanism is proposed to interpret the contrast adhesion. After being coated with a sticky perfluoroalkyl, containing methacrylate, the surfaces convert to superoleophobicity and low adhesion to a number of oils. |
Subject Area | 材料科学与物理化学 |
Funding Organization | the ‘Hundred Talents’ Program of the Chinese Academy of Sciences;the NSFC (50835009;50721062;20804055);the ‘973’ project of the Chinese Ministry of Science and Technology (2007CB607601) |
Indexed By | SCI |
Language | 英语 |
Funding Project | 材料表面与界面行为研究组 ; 复合润滑材料组 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/2118 |
Collection | 固体润滑国家重点实验室(LSL) |
Corresponding Author | Zhou F(周峰) |
Recommended Citation GB/T 7714 | Liu XJ,Wu WC,Wang XL,et al. A replication strategy for complex micro/nanostructures with superhydrophobicity and superoleophobicity and high contrast adhesion[J]. Soft Matter,2009,5:3097-3105. |
APA | 刘新杰,吴伟词,王晓龙,罗莊竹,梁永民,&周峰.(2009).A replication strategy for complex micro/nanostructures with superhydrophobicity and superoleophobicity and high contrast adhesion.Soft Matter,5,3097-3105. |
MLA | 刘新杰,et al."A replication strategy for complex micro/nanostructures with superhydrophobicity and superoleophobicity and high contrast adhesion".Soft Matter 5(2009):3097-3105. |
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