| Accessing highly linear polyethylenes by 2-(1-aryliminoethyl)-7-arylimino-6,6-dimethylcyclopenta[b]pyridylchromium(III) chlorides | |
| Department | OSSO国家重点实验室 |
| Zhang, Youfu1,2; Huang, Chuanbing2,3; Hao, Xiang2; Hu XQ(胡信全)1; Sun WH(孙文华)2,3,4; Hu XQ(胡信全); Sun WH(孙文华) | |
| 2016 | |
| Source Publication | RSC Advances
 |
| ISSN | 2046-2069 |
| Volume | 6Issue:94Pages:91401-91408 |
| Abstract | A series of 2-(1-aryliminoethyl)-7-arylimino-6,6-dimethylcyclopenta[b]pyridylchromium(III) chlorides (aryl = 2,6-Me2Ph (Cr1), 2,6-Et2Ph (Cr2), 2,6-i-Pr2Ph (Cr3), 2,4,6-Me3Ph (Cr4), 2,6-Et2-4-MePh (Cr5)) was synthesized and characterized using FT-IR and elemental analysis, and the molecular structure of complex Cr1 was confirmed by using single-crystal X-ray diffraction to present a distorted octahedral geometry around the chromium center. Upon activation with modified methylaluminoxane (MMAO) or ethylaluminium sesquichloride (EASC), all chromium pre-catalysts exhibit good activities towards ethylene polymerization for the highly linear polyethylene. |
| Subject Area | 物理化学与绿色催化 |
| DOI | 10.1039/c6ra21914d |
| Funding Organization | NationalNatural Science Foundation of China (Nos. U1362204;21473160;21374123) |
| Indexed By | SCI |
| If | 3.108 |
| Language | 英语 |
| compositor | 第四作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/20975 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） |
| Corresponding Author | Hu XQ(胡信全); Sun WH(孙文华) |
| Affiliation | 1.Zhejiang Univ Technol, Coll Chem Engn, Hangzhou 310014, Zhejiang, Peoples R China 2.Chinese Acad Sci, Key Lab Engn Plast, Beijing Natl Lab Mol Sci, Inst Chem, Beijing 100190, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 4.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China |
| Recommended Citation GB/T 7714 | Zhang, Youfu,Huang, Chuanbing,Hao, Xiang,et al. Accessing highly linear polyethylenes by 2-(1-aryliminoethyl)-7-arylimino-6,6-dimethylcyclopenta[b]pyridylchromium(III) chlorides[J]. RSC Advances,2016,6(94):91401-91408. |
| APA | Zhang, Youfu.,Huang, Chuanbing.,Hao, Xiang.,Hu XQ.,Sun WH.,...&孙文华.(2016).Accessing highly linear polyethylenes by 2-(1-aryliminoethyl)-7-arylimino-6,6-dimethylcyclopenta[b]pyridylchromium(III) chlorides.RSC Advances,6(94),91401-91408. |
| MLA | Zhang, Youfu,et al."Accessing highly linear polyethylenes by 2-(1-aryliminoethyl)-7-arylimino-6,6-dimethylcyclopenta[b]pyridylchromium(III) chlorides".RSC Advances 6.94(2016):91401-91408. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| c6ra21914d.pdf（436KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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