From Waste Biomass to Solid Support: Lignosulfonate as a Cost-Effective and Renewable Supporting Material for Catalysis | |
Department | OSSO国家重点实验室 |
Sun, Shaohuan1; Bai RX(白荣献)1; Gu YL(顾彦龙)1,2; Bai RX(白荣献); Gu YL(顾彦龙) | |
2014 | |
Source Publication | Chemistry - A European Journal |
ISSN | 0947-6539 |
Volume | 20Issue:2Pages:549-558 |
Abstract | Lignosulfonate (LS) is an organic waste generated as a byproduct of the cooking process in sulfite pulping in the manufacture of paper. In this paper, LS was used as an anionic supporting material for immobilizing cationic species, which can then be used as heterogeneous catalysts in some organic transformations. With this strategy, three lignin-supported catalysts were prepared including 1) lignin-SO3Sc(OTf)2, 2) lignin-SO3Cu(OTf), and 3) lignin-IL@NH2 (IL=ionic liquid). These solid materials were then examined in many organic transformations. It was finally found that, compared with its homogeneous counterpart as well as some other solid catalysts that are prepared by using different supports with the same metal or catalytically active species, the lignin-supported catalysts showed better performance in these reactions not only in terms of activity but also with regard to recyclability. |
Keyword | Acid Catalysis Biomass Homogeneous Catalysis Lignosulfonate Solid Catalyst |
Subject Area | 物理化学与绿色催化 |
DOI | 10.1002/chem.201303364 |
Funding Organization | National Natural Science Foundation of China (21173089;21373093);The Program for new Century Excellent Talents in the University of China (NCET-10–0383);Chutian Scholar Program of the Hubei Provincial Government and the Cooperative Innovation Center of Hubei Province |
Indexed By | SCI |
If | 5.731 |
Language | 英语 |
compositor | 第二作者单位 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/20714 |
Collection | 羰基合成与选择氧化国家重点实验室(OSSO) |
Corresponding Author | Bai RX(白荣献); Gu YL(顾彦龙) |
Affiliation | 1.Huazhong Univ Sci & Technol, Sch Chem & Chem Engn, Key Lab Large Format Battery Mat & Syst,Minist Ed, Hubei Key Lab Mat Chem & Serv Failure, Wuhan 430074, Peoples R China 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China |
Recommended Citation GB/T 7714 | Sun, Shaohuan,Bai RX,Gu YL,et al. From Waste Biomass to Solid Support: Lignosulfonate as a Cost-Effective and Renewable Supporting Material for Catalysis[J]. Chemistry - A European Journal,2014,20(2):549-558. |
APA | Sun, Shaohuan,Bai RX,Gu YL,白荣献,&顾彦龙.(2014).From Waste Biomass to Solid Support: Lignosulfonate as a Cost-Effective and Renewable Supporting Material for Catalysis.Chemistry - A European Journal,20(2),549-558. |
MLA | Sun, Shaohuan,et al."From Waste Biomass to Solid Support: Lignosulfonate as a Cost-Effective and Renewable Supporting Material for Catalysis".Chemistry - A European Journal 20.2(2014):549-558. |
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