| An Aluminum Triflate-Catalyzed Intramolecular Reaction Sequence Toward Concise Construction of the Tetrahydropyrido[1,2-a]indol-6-one Skeleton | |
| Department | OSSO国家重点实验室 |
| Wang, Jun-Jiao1; Zhou, An-Xi1; Wang, Gang-Wei1; Yang SD(杨尚东)1,2; Yang SD(杨尚东) | |
| 2014 | |
| Source Publication | Advanced Synthesis and Catalysis
 |
| ISSN | 1615-4150 |
| Volume | 356Issue:16Pages:3356-3362 |
| Abstract |
An aluminum triflate-catalyzed intramolecular reaction sequence involving protonation and Mannich-like nucleophilic addition of indoles toward the concise construction of the tetrahydropyrido[1,2-a]indol-6-one skeleton is reported. This new reaction pattern employs a carbon atom as nucleophile to form a C |
| Keyword | N-acyliminium Ions Aluminum Triflate Dearomatization Mannich-like Cyclization |
| Subject Area | 物理化学与绿色催化 |
| DOI | 10.1002/adsc.201400391 |
| Funding Organization | the NSFC (No. 21272100);Program for Changjiang Scholars and Innovative Research Team in University (PCSIRT: IRT1138);Program for New Century Excellent Talents in University (NCET-11-0215;lzujbky-2013-k07) |
| Indexed By | SCI |
| If | 5.663 |
| Language | 英语 |
| compositor | 第二作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/20707 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） |
| Corresponding Author | Yang SD(杨尚东) |
| Affiliation | 1.Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China |
| Recommended Citation GB/T 7714 | Wang, Jun-Jiao,Zhou, An-Xi,Wang, Gang-Wei,et al. An Aluminum Triflate-Catalyzed Intramolecular Reaction Sequence Toward Concise Construction of the Tetrahydropyrido[1,2-a]indol-6-one Skeleton[J]. Advanced Synthesis and Catalysis,2014,356(16):3356-3362. |
| APA | Wang, Jun-Jiao,Zhou, An-Xi,Wang, Gang-Wei,Yang SD,&杨尚东.(2014).An Aluminum Triflate-Catalyzed Intramolecular Reaction Sequence Toward Concise Construction of the Tetrahydropyrido[1,2-a]indol-6-one Skeleton.Advanced Synthesis and Catalysis,356(16),3356-3362. |
| MLA | Wang, Jun-Jiao,et al."An Aluminum Triflate-Catalyzed Intramolecular Reaction Sequence Toward Concise Construction of the Tetrahydropyrido[1,2-a]indol-6-one Skeleton".Advanced Synthesis and Catalysis 356.16(2014):3356-3362. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| Adv. Synth. Catal. 2（534KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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![[BOND]](http://onlinelibrarystatic.wiley.com/undisplayable_characters/00f8ff.gif)
C bond which bears one or even two quaternary carbons and leads to the dearomatization of indoles with high atom economy.
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