| Efficient Catalyst for Both Suzuki and Heck Cross-Coupling Reactions: Synthesis and Catalytic Behaviour of Geometry-Constrained Iminopyridylpalladium Chlorides | |
| Department | OSSO国家重点实验室 |
| Tang, Yujie1; Zeng, Yanning2; Hu, Qingxia1; Huang, Fang1,2; Jin, Liqun1; Mo WM(莫卫民)1; Sun N(孙楠)1; Hu BX(胡宝祥)1; Shen ZL(沈振陆)1; Hu XQ(胡信全)1,3; Sun WH(孙文华)2,3; Hu XQ(胡信全); Sun WH(孙文华) | |
| 2016 | |
| Source Publication | Advanced Synthesis and Catalysis
 |
| ISSN | 1615-4150 |
| Volume | 358Issue:16Pages:2642-2651 |
| Abstract | A series of geometry-constrained iminopyridyl-palladium chlorides were synthesized and characterized. These phosphine-free palladium complexes were explored for their catalytic activities in both Suzuki and Heck cross-coupling reactions, achieving turnover numbers as high as 106 towards various aryl bromides, even those containing various functionalities. In addition, the influence of substituents with steric and electronic factors was reflected by the differences observed in their activities. |
| Keyword | Iminopyridyl Complexes Palladium Heck Reaction Suzuki Reaction |
| Subject Area | 物理化学与绿色催化 |
| DOI | 10.1002/adsc.201600294 |
| Funding Organization | the National Natural Science Foundation of China (21473160;21376224);Zhejiang University of Technology and Qianjiang Scholar Program funded by Zhejiang Province, China |
| Indexed By | SCI |
| If | 5.646 |
| Language | 英语 |
| compositor | 第三作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/20684 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） |
| Corresponding Author | Jin, Liqun; Hu XQ(胡信全); Sun WH(孙文华) |
| Affiliation | 1.Zhejiang Univ Technol, Coll Chem Engn, Hangzhou 310032, Zhejiang, Peoples R China 2.Chinese Acad Sci, Inst Chem, Key Lab Engn Plast and Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China 3.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China |
| Recommended Citation GB/T 7714 | Tang, Yujie,Zeng, Yanning,Hu, Qingxia,et al. Efficient Catalyst for Both Suzuki and Heck Cross-Coupling Reactions: Synthesis and Catalytic Behaviour of Geometry-Constrained Iminopyridylpalladium Chlorides[J]. Advanced Synthesis and Catalysis,2016,358(16):2642-2651. |
| APA | Tang, Yujie.,Zeng, Yanning.,Hu, Qingxia.,Huang, Fang.,Jin, Liqun.,...&孙文华.(2016).Efficient Catalyst for Both Suzuki and Heck Cross-Coupling Reactions: Synthesis and Catalytic Behaviour of Geometry-Constrained Iminopyridylpalladium Chlorides.Advanced Synthesis and Catalysis,358(16),2642-2651. |
| MLA | Tang, Yujie,et al."Efficient Catalyst for Both Suzuki and Heck Cross-Coupling Reactions: Synthesis and Catalytic Behaviour of Geometry-Constrained Iminopyridylpalladium Chlorides".Advanced Synthesis and Catalysis 358.16(2016):2642-2651. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| LZ01029410.pdf（1647KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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