Synthesis of EDTA-assisted CeVO4 nanorods as robust peroxidase mimics towards colorimetric detection of H2O2 | |
Department | 清洁能源化学与材料实验室 |
Ju P(鞠鹏)1,2; Yu YZ(于延珍)3; Wang M(王敏)1,4; Zhao Y(赵雲)1; Zhang D(张盾)5; Sun CJ(孙承君)3,6; Han XX(韩修训)1,2; Sun CJ(孙承君); Han XX(韩修训) | |
2016 | |
Source Publication | Journal of Materials Chemistry B |
ISSN | 2050-750X |
Volume | 4Issue:38Pages:6316-6325 |
Abstract | In this paper, CeVO4 materials were developed as highly efficient biomimetic catalysts for the first time to detect H2O2. These CeVO4 materials were prepared by a facile hydrothermal method with the assistance of EDTA, exhibiting different morphologies, surface properties, and distinct peroxidase mimetic activities. Among them, CeVO4-2 nanorods (NRs) were proved to display the best intrinsic peroxidase-like property compared to other CeVO4 samples due to their more negative potential and larger BET specific surface area, which could efficiently catalyze the oxidation of 3,3′,5,5′-tetramethylbenzidine (TMB) in the presence of H2O2 to generate a blue oxide. Based on the excellent peroxidase mimetic catalytic activity of CeVO4-2 NRs, a simple, convenient and visual H2O2 detection system was successfully established. The detection limit of H2O2 could reach as low as 0.07 μM. Moreover, the CeVO4-2 NR-based assay system presented an excellent selectivity, practicability, long-term stability, and reusability. The peroxidase-like catalytic mechanism of CeVO4-2 NRs was proposed on the basis of active species trapping experiments. This work provides a novel, convenient, rapid, and ultrasensitive system for the colorimetric detection of H2O2, which has a bright prospect in H2O2 detection and biomedical analysis. |
Subject Area | 材料科学与物理化学 |
DOI | 10.1039/c6tb01881e |
Funding Organization | the ‘‘Top Hundred Talents Program’’ of Chinese Academy of Sciences (CAS);the National Natural Science Foundation of China (Grant No. 41476068);The National Natural Science Foundation of China-Shandong Joint Funded Project (Grant No. U1406403);Qingdao Talent (Grant No. 13-CX-20);the Taishan Scholar Program |
Indexed By | SCI |
If | 4.543 |
Language | 英语 |
Funding Project | 光电材料与器件研究组 |
compositor | 第一作者单位 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/20477 |
Collection | 清洁能源化学与材料实验室 |
Corresponding Author | Sun CJ(孙承君); Han XX(韩修训) |
Affiliation | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, Lab Clean Energy Chem & Mat, 18 Tianshui Middle Rd, Lanzhou 730000, Peoples R China 2.Qingdao Ctr Resource Chem & New Mat, 36 Jinshui Rd, Qingdao 266100, Peoples R China 3.State Ocean Adm, Inst Oceanog 1, Marine Ecol Ctr, 6 Xianxialing Rd, Qingdao 266061, Peoples R China 4.Univ Chinese Acad Sci, 19 Jia Yuquan Rd, Beijing 100039, Peoples R China 5.Chinese Acad Sci, Inst Oceanol, Key Lab Marine Environm Corros & Biofouling, 7 Nanhai Rd, Qingdao 266071, Peoples R China 6.Qingdao Natl Lab Marine Sci & Technol, Lab Marine Drugs & Bioprod, Qingdao 266071, Peoples R China |
Recommended Citation GB/T 7714 | Ju P,Yu YZ,Wang M,et al. Synthesis of EDTA-assisted CeVO4 nanorods as robust peroxidase mimics towards colorimetric detection of H2O2[J]. Journal of Materials Chemistry B,2016,4(38):6316-6325. |
APA | Ju P.,Yu YZ.,Wang M.,Zhao Y.,Zhang D.,...&韩修训.(2016).Synthesis of EDTA-assisted CeVO4 nanorods as robust peroxidase mimics towards colorimetric detection of H2O2.Journal of Materials Chemistry B,4(38),6316-6325. |
MLA | Ju P,et al."Synthesis of EDTA-assisted CeVO4 nanorods as robust peroxidase mimics towards colorimetric detection of H2O2".Journal of Materials Chemistry B 4.38(2016):6316-6325. |
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Synthesis of EDTA-as(6937KB) | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text |
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