Transition-Metal-Catalyzed Redox-Neutral and Redox-Green C-H Bond Functionalization | |
Department | OSSO国家重点实验室 |
Wang, Hongli; Huang HM(黄汉民); Huang HM(黄汉民) | |
2016 | |
Source Publication | Chemical Record |
ISSN | 1527-8999 |
Volume | 16Issue:4Pages:1807-1818 |
Abstract | Transition-metal-catalyzed C–H bond functionalization has become one of the most promising strategies to prepare complex molecules from simple precursors. However, the utilization of environmentally unfriendly oxidants in the oxidative C–H bond functionalization reactions reduces their potential applications in organic synthesis. This account describes our recent efforts in the development of a redox-neutral C–H bond functionalization strategy for direct addition of inert C–H bonds to unsaturated double bonds and a redox-green C–H bond functionalization strategy for realization of oxidative C–H functionalization with O2 as the sole oxidant, aiming to circumvent the problems posed by utilizing environmentally unfriendly oxidants. In principle, these redox-neutral and redox-green strategies pave the way for establishing new environmentally benign transition-metal-catalyzed C–H bond functionalization strategies. |
Keyword | Homogeneous Catalysis Nucleophilic Addition Redox Chemistry Synthetic Methods Transition Metals |
Subject Area | 物理化学与绿色催化 |
DOI | 10.1002/tcr.201500274 |
Funding Organization | the Chinese Academy of Sciences;the National Natural Science Foundation of China (21133011;21222203;21172226;21372231) |
Indexed By | SCI |
If | 3.855 |
Language | 英语 |
compositor | 第一作者单位 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/20473 |
Collection | 羰基合成与选择氧化国家重点实验室(OSSO) |
Corresponding Author | Huang HM(黄汉民) |
Affiliation | Chinese Acad Sci, State Key Lab Oxo Synth & Select Oxidat, Lanzhou Inst Chem Phys, Lanzhou 730000, Peoples R China |
Recommended Citation GB/T 7714 | Wang, Hongli,Huang HM,Huang HM. Transition-Metal-Catalyzed Redox-Neutral and Redox-Green C-H Bond Functionalization[J]. Chemical Record,2016,16(4):1807-1818. |
APA | Wang, Hongli,Huang HM,&黄汉民.(2016).Transition-Metal-Catalyzed Redox-Neutral and Redox-Green C-H Bond Functionalization.Chemical Record,16(4),1807-1818. |
MLA | Wang, Hongli,et al."Transition-Metal-Catalyzed Redox-Neutral and Redox-Green C-H Bond Functionalization".Chemical Record 16.4(2016):1807-1818. |
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LZ01029309.pdf(986KB) | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text |
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