| Synthesis of Densely Substituted 1,3-Butadienes through AcidCatalyzed Alkenylations of a-Oxoketene Dithioacetals with Aldehydes | |
| Department | OSSO国家重点实验室 |
| Liu, Changhui1; Gu YL(顾彦龙)1,2; Gu YL(顾彦龙) | |
| 2014 | |
| Source Publication | Journal of Organic Chemistry
 |
| ISSN | 0022-3263 |
| Volume | 79Issue:20Pages:9619-9627 |
| Abstract | Aldehydes were proved to be viable reagents for implementing alkenylation of α-oxoketene dithioacetals. AlCl3 was found to be the best catalyst. The established reaction opened an avenue to access densely substituted 1,3-butadiene derivatives. The obtained product bears multiple reactive sites that can be converted into various valuable molecules. |
| Subject Area | 物理化学与绿色催化 |
| DOI | 10.1021/jo5017234 |
| Funding Organization | the National Natural Science Foundation of China (21173089;21373093);the fundamental research funds the central universities in China (2014ZZGH019) |
| Indexed By | SCI |
| If | 4.721 |
| Language | 英语 |
| compositor | 第二作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/20320 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） |
| Corresponding Author | Gu YL(顾彦龙) |
| Affiliation | 1.Huazhong Univ Sci & Technol, Sch Chem & Chem Engn, Minist Educ, Key Lab Large Format Battery Mat & Syst, Wuhan 430074, Peoples R China 2.Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China |
| Recommended Citation GB/T 7714 | Liu, Changhui,Gu YL,Gu YL. Synthesis of Densely Substituted 1,3-Butadienes through AcidCatalyzed Alkenylations of a-Oxoketene Dithioacetals with Aldehydes[J]. Journal of Organic Chemistry,2014,79(20):9619-9627. |
| APA | Liu, Changhui,Gu YL,&顾彦龙.(2014).Synthesis of Densely Substituted 1,3-Butadienes through AcidCatalyzed Alkenylations of a-Oxoketene Dithioacetals with Aldehydes.Journal of Organic Chemistry,79(20),9619-9627. |
| MLA | Liu, Changhui,et al."Synthesis of Densely Substituted 1,3-Butadienes through AcidCatalyzed Alkenylations of a-Oxoketene Dithioacetals with Aldehydes".Journal of Organic Chemistry 79.20(2014):9619-9627. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| jo5017234.pdf（1159KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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