LICP OpenIR  > 羰基合成与选择氧化国家重点实验室(OSSO)
Regio- and Stereoselective Oxysulfonylation of Allenes
DepartmentOSSO国家重点实验室
Huang, Zhiyuan1; Lu, Qingquan1; Liu, Yichang1; Liu, Dong1; Zhang, Jian1; Lei AW(雷爱文)1,2; Lei AW(雷爱文)
2016
Source PublicationOrganic Letters
ISSN1523-7060
Volume18Issue:16Pages:3940-3943
Abstract

A highly regio- and stereoselective oxysulfonylation of allenes was developed that provided direct access to 2-sulfonyl allylic alcohols in good yields. By means of dioxygen activation, selective difunctionlization of allenes could be successfully achieved under mild metal-free conditions. Preliminary mechanistic investigation disclosed that this transformation probably goes through a radical process.

Subject Area物理化学与绿色催化
DOI10.1021/acs.orglett.61301575
Funding Organizationthe 973 Program (2012CB725302);the National Natural Science Foundation of China (21390400;21272180;21302148);the Research Fund for the Doctoral Program of Higher Education of China (20120141130002);the Ministry of Science and Technology of China (2012YQ120060);the Program of Introducing Talents of Discipline to Universities of China (111 Program)
Indexed BySCI
If6.579
Language英语
compositor第二作者单位
Citation statistics
Cited Times:44[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.licp.cn/handle/362003/20313
Collection羰基合成与选择氧化国家重点实验室(OSSO)
Corresponding AuthorLei AW(雷爱文)
Affiliation1.Wuhan Univ, IAS, Coll Chem & Mol Sci, Wuhan 430072, Hubei, Peoples R China
2.Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China
Recommended Citation
GB/T 7714
Huang, Zhiyuan,Lu, Qingquan,Liu, Yichang,et al. Regio- and Stereoselective Oxysulfonylation of Allenes[J]. Organic Letters,2016,18(16):3940-3943.
APA Huang, Zhiyuan.,Lu, Qingquan.,Liu, Yichang.,Liu, Dong.,Zhang, Jian.,...&雷爱文.(2016).Regio- and Stereoselective Oxysulfonylation of Allenes.Organic Letters,18(16),3940-3943.
MLA Huang, Zhiyuan,et al."Regio- and Stereoselective Oxysulfonylation of Allenes".Organic Letters 18.16(2016):3940-3943.
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