Efficient Benzylic and Aliphatic C-H Oxidation with Selectivity for Methylenic Sites Catalyzed by a Bioinspired Manganese Complex

doi:10.1021/ol4037083

	Efficient Benzylic and Aliphatic C-H Oxidation with Selectivity for Methylenic Sites Catalyzed by a Bioinspired Manganese Complex
Department	OSSO国家重点实验室
	Shen DY(沈都益)1,2 ; Miao CX(苗成霞)1 ; Wang SF(王寿峰)1 ; Xia CG(夏春谷)1 ; Sun W(孙伟)1 ; Sun W(孙伟)
	2014
Source Publication	Organic Letters
ISSN	1523-7060
Volume	16 Issue:4 Pages:1108-1111
Abstract	A benzimidazole-based nonheme manganese complex efficiently catalyzes benzylic, aliphatic C–H as well as tertiary C–H oxidation with hydrogen peroxide as the oxidant in the presence of acetic acid as additive. ¹⁸O labeling experiments suggest the reaction may proceed via a high-valent manganese-oxo intermediate.
Subject Area	物理化学与绿色催化
DOI	10.1021/ol4037083
Funding Organization	the National Natural Science Foundation of China (No. 21073210;21133011;21103206)
Indexed By	SCI
If	6.364
Language	英语
Funding Project	生物与仿生催化课题组;均相催化课题组
compositor	第一作者单位
Citation statistics	Cited Times:124[WOS] [WOS Record] [Related Records in WOS]
Document Type	期刊论文
Identifier	http://ir.licp.cn/handle/362003/20278
Collection	羰基合成与选择氧化国家重点实验室（OSSO）
Corresponding Author	Sun W(孙伟)
Affiliation	1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
Recommended Citation GB/T 7714	Shen DY,Miao CX,Wang SF,et al. Efficient Benzylic and Aliphatic C-H Oxidation with Selectivity for Methylenic Sites Catalyzed by a Bioinspired Manganese Complex[J]. Organic Letters,2014,16(4):1108-1111.
APA	Shen DY,Miao CX,Wang SF,Xia CG,Sun W,&孙伟.(2014).Efficient Benzylic and Aliphatic C-H Oxidation with Selectivity for Methylenic Sites Catalyzed by a Bioinspired Manganese Complex.Organic Letters,16(4),1108-1111.
MLA	Shen DY,et al."Efficient Benzylic and Aliphatic C-H Oxidation with Selectivity for Methylenic Sites Catalyzed by a Bioinspired Manganese Complex".Organic Letters 16.4(2014):1108-1111.

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