| Solvent-Free Selective Condensations Based on the Formation of the Olefinic (C = C) Bond Catalyzed by Organocatalyst | |
| Department | OSSO国家重点实验室 |
Song HY(宋河远)1,2 ; Jin RH(靳荣华)1; Jin FX(金福祥)1; Kang MR(康美荣)1; Li Z(李臻)1; Chen J(陈静)1; Li Z(李臻); Chen J(陈静)
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| 2016 | |
| Source Publication | Catalysts
 |
| ISSN | 2073-4344 |
| Volume | 6Issue:7Pages:106(1-8) |
| Abstract | Pyrrolidine and its derivatives were used to catalyze aldol and Knoevenagel condensations for the formation of the olefinic (C = C) bond under solvent-free conditions. The 3-pyrrolidinamine showed high activity and afforded excellent yields of alpha, beta-unsaturated compounds. The aldol condensation of aromatic/heterocyclic aldehydes with ketones affords enones in high conversion (99.5%) and selectivity (92.7%). Good to excellent yields of alpha, beta-unsaturated compounds were obtained in the Knoevenagel condensation of aldehydes with methylene-activated substrates. |
| Keyword | Aldol Condensation Knoevenagel Condensation Organocatalysis Solvent-free Condition Ketone Aldehyde |
| Subject Area | 物理化学与绿色催化 |
| DOI | 10.3390/catal6070106 |
| Funding Organization | the National Natural Science Foundation of China (Project No. 21473225) |
| Indexed By | SCI |
| If | 3.082 |
| Language | 英语 |
| Funding Project | 分子催化与技术课题组;均相催化课题组 |
| compositor | 第一作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/20224 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） |
| Corresponding Author | Li Z(李臻); Chen J(陈静) |
| Affiliation | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China 2.Univ Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China |
| Recommended Citation GB/T 7714 | Song HY,Jin RH,Jin FX,et al. Solvent-Free Selective Condensations Based on the Formation of the Olefinic (C = C) Bond Catalyzed by Organocatalyst[J]. Catalysts,2016,6(7):106(1-8). |
| APA | Song HY.,Jin RH.,Jin FX.,Kang MR.,Li Z.,...&陈静.(2016).Solvent-Free Selective Condensations Based on the Formation of the Olefinic (C = C) Bond Catalyzed by Organocatalyst.Catalysts,6(7),106(1-8). |
| MLA | Song HY,et al."Solvent-Free Selective Condensations Based on the Formation of the Olefinic (C = C) Bond Catalyzed by Organocatalyst".Catalysts 6.7(2016):106(1-8). |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| catalysts-06-00106.p（4707KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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