LICP OpenIR  > 羰基合成与选择氧化国家重点实验室(OSSO)
Asymmetric Synthesis of Chiral Atropisomeric Bis-Aryl Organophosphorus from Menthyl H-Phosphinate
DepartmentOSSO国家重点实验室
Ma YN(马艳娜)1; Yang SD(杨尚东)1,2
2016
Source PublicationChemical Record
ISSN1527-8999
Volume16Issue:2Pages:977-986
Abstract

This review describes new methods for the synthesis of chiral monophosphine ligands with menthyl phenylphosphinate as a chiral auxiliary through asymmetric Suzuki-Miyaura cross-coupling reactions and asymmetric C–H functionalization. The chiral menthyl phenylphosphinate as a chiral auxiliary is easy to prepare and the menthyl group can easily be transformed into other functional groups, with the chiral center synchronously remaining. These methodologies provide highly efficient and practical strategies for the synthesis of novel axially chiral biaryl monophosphine oxides and their corresponding phosphines. Meanwhile, these reactions are easy to handle and exhibit wide scope for substrates with excellent diastereomeric ratios.

KeywordAsymmetric C-h Functionalization Asymmetric Suzuki-miyaura Cross-coupling Chiral Auxiliaries Menthyl Phenylphosphinate Phosphine Ligands
Subject Area物理化学与绿色催化
DOI10.1002/tcr.201500242
Funding Organizationthe NSFC (Nos. 21272100;21472076)
Indexed BySCI
If3.855
Language英语
compositor第二作者单位
Citation statistics
Cited Times:22[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.licp.cn/handle/362003/20096
Collection羰基合成与选择氧化国家重点实验室(OSSO)
Affiliation1.Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China
2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China
Recommended Citation
GB/T 7714
Ma YN,Yang SD. Asymmetric Synthesis of Chiral Atropisomeric Bis-Aryl Organophosphorus from Menthyl H-Phosphinate[J]. Chemical Record,2016,16(2):977-986.
APA Ma YN,&Yang SD.(2016).Asymmetric Synthesis of Chiral Atropisomeric Bis-Aryl Organophosphorus from Menthyl H-Phosphinate.Chemical Record,16(2),977-986.
MLA Ma YN,et al."Asymmetric Synthesis of Chiral Atropisomeric Bis-Aryl Organophosphorus from Menthyl H-Phosphinate".Chemical Record 16.2(2016):977-986.
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