| A D-Camphor-Based Schiff Base as a Highly Efficient N,P Ligand for Enantioselective Palladium-Catalyzed Allylic Substitutions | |
| Department | OSSO国家重点实验室 |
| Liu, Qiao-Ling1; Chen, Weifeng1; Jiang, Qun-Ying1; Bai XF(柏惺峰)1,2,3; Li, Zhifang1; Xu, Zheng1; Xu LW(徐利文)1,2,3; Xu LW(徐利文) | |
| 2016 | |
| Source Publication | ChemCatChem
 |
| ISSN | 1867-3880 |
| Volume | 8Issue:8Pages:1495-1499 |
| Abstract | New Schiff bases derived from chiral d-camphor were determined to be effective phosphine ligands for the asymmetric palladium-catalyzed allylic alkylation of activated methylene compounds, the allylic etherification of alcohols, and the allylic amination of primary amines or secondary amines, in which the corresponding products with various functional groups were achieved in good yields with excellent enantioselectivities (up to >99 % ee). Remarkably, the palladium catalyst derived from Schiff base L2 afforded the highest level of enantioselectivity reported to date for allylic substitution reactions, including allylic etherification and allylic amination, which revealed the privileged role of d-camphor-derived Schiff bases in palladium-catalyzed allylic substitution reactions. |
| Keyword | Allylic Compounds Asymmetric Catalysis Palladium n Schiff Bases p Ligands |
| Subject Area | 物理化学与绿色催化 |
| DOI | 10.1002/cctc.201600084 |
| Funding Organization | the National Natural Science Founder of China (No. 21173064;21202031;21472031);Zhejiang Provincial Natural Science Foundation of China (LR148030001) |
| Indexed By | SCI |
| If | 4.803 |
| Language | 英语 |
| compositor | 第二作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/20093 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） |
| Corresponding Author | Xu LW(徐利文) |
| Affiliation | 1.Hangzhou Normal Univ, Minist Educ, Key Lab Organosilicon Chem & Mat Technol, 1378 Wenyi West Rd,Sci Pk HZNU, Hangzhou, Zhejiang, Peoples R China 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Beijing, Peoples R China 3.Univ Chinese Acad Sci, Beijing, Peoples R China |
| Recommended Citation GB/T 7714 | Liu, Qiao-Ling,Chen, Weifeng,Jiang, Qun-Ying,et al. A D-Camphor-Based Schiff Base as a Highly Efficient N,P Ligand for Enantioselective Palladium-Catalyzed Allylic Substitutions[J]. ChemCatChem,2016,8(8):1495-1499. |
| APA | Liu, Qiao-Ling.,Chen, Weifeng.,Jiang, Qun-Ying.,Bai XF.,Li, Zhifang.,...&徐利文.(2016).A D-Camphor-Based Schiff Base as a Highly Efficient N,P Ligand for Enantioselective Palladium-Catalyzed Allylic Substitutions.ChemCatChem,8(8),1495-1499. |
| MLA | Liu, Qiao-Ling,et al."A D-Camphor-Based Schiff Base as a Highly Efficient N,P Ligand for Enantioselective Palladium-Catalyzed Allylic Substitutions".ChemCatChem 8.8(2016):1495-1499. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| LZ01029055.pdf（894KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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