A formaldehyde carbonyl groups-modified self-crosslinked-polystyrene resin: Synthesis, adsorption and separation properties | |
Department | 中科院西北特色植物资源化学重点实验室/甘肃省天然药物重点实验室 |
Li XT(李晓婷)1,2; Liu YF(刘永峰)1,3; Di DL(邸多隆)1,3; Wang GH(王高红)1,2; Liu Y(刘毅)1,3; Di DL(邸多隆) | |
2016 | |
Source Publication | Colloids and Surfaces A: Physicochemical and Engineering Aspects |
ISSN | 0927-7757 |
Volume | 500Pages:1-9 |
Abstract | Based on our previous work and calculational chemistry, the pore-size distribution is the key factor which influences glabridin uptakes on resins. In addition, micropores and mesopores in the range of 1.8–5.4 nm are proper for glabridin adsorption. Based on this, a series of novel microporous and mesoporous self-crosslinked polystyrene resins (named as XT2) were synthesized by Friedel–Crafts reaction after different reaction time and utilized to adsorb glabridin in aqueous solution. The adsorption behaviors of the synthetic resins were studied systematically in terms of adsorption capacity, equilibrium time, isotherm adsorption and regeneration properties and compared with a commercial adsorbent (BMKB-1) which was screened out as the optimal macroporous adsorption resin (MAR) for glabridin based on our previous work. The characteristic methods of BET surface area, pore size distribution, Fourier transform infrared spectroscopy and scanning electron microscopy were investigated to analyze the resins and adsorption process. The glabridin uptakes on XT2-10 were remarkably larger than those of macroporous adsorption resin BMKB-1. The maximum adsorption capacity of XT2-10 is up to 43.69 mg/g for glabridin. The adsorption isotherms could be well described by the Freundlich model, and the adsorption kinetics were fitted by both pseudo-second-order kinetic equation and intra-particle diffusion model. The adsorption mechanism was a synergistic effect of specific surface area, molecular sieving effect, and multiple adsorption interactions including hydrogen bonding and π–π stacking. The glabridin uptakes decreased to approximately 93.23% after five cycles of adsorption–desorption, exhibiting an excellent reusability and remarkable regeneration. Based on these results, this research not only opens up the possibility of synthesizing microporous and mesoporous self-crosslinked polystyrene resins, but also provides guidance for understanding the adsorption mechanism of purification of flavones from herbal plants. |
Keyword | Self-crosslinked Resin Microporous Glabridin Adsorption Kinetics Adsorption Isotherm |
Subject Area | 分析化学与药物化学 |
DOI | 10.1016/j.colsurfa.2016.03.061 |
Funding Organization | the National Natural Sciences Foundation of China (NSFC No. 20974116;21374128);the “Hundred Talents Program” of the Chinese Academy of Sciences (CAS);the National High Technology Research and Development Program of China (863 No. 2014AA022203) |
Indexed By | SCI |
If | 2.714 |
Language | 英语 |
Funding Project | 药物工艺标准研究组 |
compositor | 第一作者单位 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/20089 |
Collection | 中科院西北特色植物资源化学重点实验室/甘肃省天然药物重点实验室 |
Corresponding Author | Di DL(邸多隆) |
Affiliation | 1.Key Laboratory of Chemistry of Northwestern Plant Resources and Key Laboratory for Natural Medicine of Gansu Province, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, 18 Tianshui Middle Road, Lanzhou 730000, People’s Republic of China 2.Graduate University of the Chinese Academy of Sciences, 19A Yuquan Road, Beijing 100049, People’s Republic of China 3.Centre of Resource Chemical and New Material, 36 Jinshui Road, Qingdao 266100, People’s Republic of China |
Recommended Citation GB/T 7714 | Li XT,Liu YF,Di DL,et al. A formaldehyde carbonyl groups-modified self-crosslinked-polystyrene resin: Synthesis, adsorption and separation properties[J]. Colloids and Surfaces A: Physicochemical and Engineering Aspects,2016,500:1-9. |
APA | Li XT,Liu YF,Di DL,Wang GH,Liu Y,&邸多隆.(2016).A formaldehyde carbonyl groups-modified self-crosslinked-polystyrene resin: Synthesis, adsorption and separation properties.Colloids and Surfaces A: Physicochemical and Engineering Aspects,500,1-9. |
MLA | Li XT,et al."A formaldehyde carbonyl groups-modified self-crosslinked-polystyrene resin: Synthesis, adsorption and separation properties".Colloids and Surfaces A: Physicochemical and Engineering Aspects 500(2016):1-9. |
Files in This Item: | ||||||
File Name/Size | DocType | Version | Access | License | ||
1-s2.0-S092777571630(1986KB) | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text |
Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.
Edit Comment