| Solvent-promoted catalyst-free N-formylation of amines using carbon dioxide under ambient conditions | |
| Department | OSSO国家重点实验室 |
Lv, Hui1,2; Xing Q(邢琦)2 ; Yue CT(岳成涛)2; Lei, Ziqiang1; Li FW(李福伟)2; Li FW(李福伟)
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| 2016 | |
| Source Publication | Chemical Communications
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| ISSN | 1359-7345 |
| Volume | 52Issue:39Pages:6545-6548 |
| Abstract | An unprecedented catalyst-free formylation of amines using CO2 and hydrosilanes was developed. The solvent plays a vital role in promoting the interaction of amines with hydrosilanes and subsequent CO2 insertion, thus facilitating the simultaneous activation of N–H and Si–H bonds. Based on relevant mechanistic studies, a plausible mechanism involving a silyl carbamate intermediate is proposed. |
| Subject Area | 物理化学与绿色催化 |
| DOI | 10.1039/c6cc01234e |
| Funding Organization | the Chinese Academy of Sciences;the National Natural Science Foundation of China (21133011;21373246;21522309) |
| Indexed By | SCI |
| If | 6.319 |
| Language | 英语 |
| Funding Project | 均相催化课题组 |
| compositor | 第二作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/20083 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） 苏州研究院 |
| Corresponding Author | Lei, Ziqiang; Li FW(李福伟) |
| Affiliation | 1.Northwest Normal Univ, Coll Chem & Chem Engn, Minist Educ, Key Lab Ecoenvironm Related Polymer Mat, Lanzhou 730070, Peoples R China 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, Suzhou Res Inst, Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China |
| Recommended Citation GB/T 7714 | Lv, Hui,Xing Q,Yue CT,et al. Solvent-promoted catalyst-free N-formylation of amines using carbon dioxide under ambient conditions[J]. Chemical Communications,2016,52(39):6545-6548. |
| APA | Lv, Hui,Xing Q,Yue CT,Lei, Ziqiang,Li FW,&李福伟.(2016).Solvent-promoted catalyst-free N-formylation of amines using carbon dioxide under ambient conditions.Chemical Communications,52(39),6545-6548. |
| MLA | Lv, Hui,et al."Solvent-promoted catalyst-free N-formylation of amines using carbon dioxide under ambient conditions".Chemical Communications 52.39(2016):6545-6548. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| c6cc01234e.pdf（1977KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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