| A Mild TEMPO-Catalyzed Aerobic Oxidative Conversion of Aldehydes into Nitriles | |
| Department | OSSO国家重点实验室 |
| Fang, Chaojie1; Li, Meichao1; Hu XQ(胡信全)1,2; Mo WM(莫卫民)1; Hu BX(胡宝祥)1; Sun N(孙楠)1; Jin, Liqun1; Shen ZL(沈振陆)1 | |
| 2016 | |
| Source Publication | Advanced Synthesis and Catalysis
 |
| ISSN | 1615-4150 |
| Volume | 358Issue:7Pages:1157-1163 |
| Abstract | An efficient method to prepare nitriles from aldehydes using hexamethyldisilazane (HMDS) as the nitrogen source has been developed. The reactions were performed with 2,2,6,6-tetramethylpiperidine l-oxyl (TEMPO) as the catalyst, NaNO2 or TBN as the co-catalyst, and molecular oxygen as the terminal oxidant under mild conditions. A variety of aromatic, heteroaromatic, aliphatic and allylic aldehydes could be converted into their corresponding nitriles in good to excellent yields. |
| Keyword | Aldehydes Hexamethyldisilazane (Hmds) Nitriles Oxidation Oxygen 2 2 6 6-tetramethylpiperidine 1-oxyl (Tempo) |
| Subject Area | 物理化学与绿色催化 |
| DOI | 10.1002/adsc.201501130 |
| Funding Organization | National Natural Science Foundation of China (21376224;21206147);Hangzhou Qianjiang Distinguished Experts Project |
| Indexed By | SCI |
| If | 5.646 |
| Language | 英语 |
| compositor | 第二作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/19999 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） |
| Affiliation | 1.Zhejiang Univ Technol, Coll Chem Engn, Hangzhou 310014, Zhejiang, Peoples R China 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China |
| Recommended Citation GB/T 7714 | Fang, Chaojie,Li, Meichao,Hu XQ,et al. A Mild TEMPO-Catalyzed Aerobic Oxidative Conversion of Aldehydes into Nitriles[J]. Advanced Synthesis and Catalysis,2016,358(7):1157-1163. |
| APA | Fang, Chaojie.,Li, Meichao.,Hu XQ.,Mo WM.,Hu BX.,...&Shen ZL.(2016).A Mild TEMPO-Catalyzed Aerobic Oxidative Conversion of Aldehydes into Nitriles.Advanced Synthesis and Catalysis,358(7),1157-1163. |
| MLA | Fang, Chaojie,et al."A Mild TEMPO-Catalyzed Aerobic Oxidative Conversion of Aldehydes into Nitriles".Advanced Synthesis and Catalysis 358.7(2016):1157-1163. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| LZ01028973.pdf（526KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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