Functional Ionic Liquids as Efficient and Recyclable Catalysts for the Methylation of Formaldehyde with Aromatics | |
Department | OSSO国家重点实验室 |
Song HY(宋河远)1,2; Jin FX(金福祥)1; Jin RH(靳荣华)1; Kang MR(康美荣)1; Li Z(李臻)1; Chen J(陈静)1; Li Z(李臻); Chen J(陈静) | |
2016 | |
Source Publication | Catalysis Letters |
ISSN | 1011-372X |
Volume | 146Issue:7Pages:1264-1272 |
Abstract | Methylation of formaldehyde with various aromatics under functional ionic liquids catalysis has been developed. Among the ionic liquids investigated, triphenyl-(4-sulfobutyl)-phosphonium triflate ([TTPBs][CF3SO3]) showed high activity and afforded excellent yields of diarylmethane derivatives. A mechanism for the catalytic performance of [TTPBs][CF3SO3] is proposed. Besides, the catalyst can simply be separated from the reaction mixture by centrifugation and be recycled ten times without noticeable loss of activity. |
Keyword | Formaldehyde Methylation Diarylmethane Ionic Liquids |
Subject Area | 物理化学与绿色催化 |
DOI | 10.1007/s10562-016-1750-5 |
Funding Organization | the National Natural Science Foundation of China (Project No. 21473225;21133011) |
Indexed By | SCI |
If | 2.799 |
Language | 英语 |
Funding Project | 分子催化与技术课题组 |
compositor | 第一作者单位 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/19806 |
Collection | 羰基合成与选择氧化国家重点实验室(OSSO) |
Corresponding Author | Li Z(李臻); Chen J(陈静) |
Affiliation | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
Recommended Citation GB/T 7714 | Song HY,Jin FX,Jin RH,et al. Functional Ionic Liquids as Efficient and Recyclable Catalysts for the Methylation of Formaldehyde with Aromatics[J]. Catalysis Letters,2016,146(7):1264-1272. |
APA | Song HY.,Jin FX.,Jin RH.,Kang MR.,Li Z.,...&陈静.(2016).Functional Ionic Liquids as Efficient and Recyclable Catalysts for the Methylation of Formaldehyde with Aromatics.Catalysis Letters,146(7),1264-1272. |
MLA | Song HY,et al."Functional Ionic Liquids as Efficient and Recyclable Catalysts for the Methylation of Formaldehyde with Aromatics".Catalysis Letters 146.7(2016):1264-1272. |
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Catal Lett 2016 146.(808KB) | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text |
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