Lewis Acid Catalyzed [4+3] Cycloaddition of Propargylic Alcohols with Azides | |
Department | 固体润滑国家重点实验室 |
Han, Ya-Ping1; Song XR(宋贤荣)2; Qiu, Yi-Feng1; Zhang, Heng-Rui1; Li, Lian-Hua1; Jin, Dong-Po1; Sun, Xiao-Qing1; Liu XY(刘雪原)1; Liang YM(梁永民)1,3; Liang YM(梁永民) | |
2016 | |
Source Publication | Organic Letters |
ISSN | 1523-7060 |
Volume | 18Issue:5Pages:940-943 |
Abstract | An unprecedented Lewis acid catalyzed [4 + 3] cycloaddition reaction is described that provides a straightforward route to polycyclic products containing an imine-based indole azepine scaffold, starting from readily available internal tertiary alkynols and azides. This cycloaddition protocol provides efficient and atom-economical access to a new class of fascinating imine-containing products in satisfactory yields, which has shown good application in the construction of seven-membered N-heterocycles. |
Subject Area | 材料科学与物理化学 |
DOI | 10.1021/acs.orglett.5b03657 |
Funding Organization | the National Natural Science Foundation (NSF 21272101;21472073);the "111" Project;J1103307;Program for Changjiang Scholars;the Fundamental Research Funds for the Central Universities (lzujbky-2014-194);Innovative Research Team in University (IRT1138) |
Indexed By | SCI |
If | 6.579 |
Language | 英语 |
compositor | 第三作者单位 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/19778 |
Collection | 固体润滑国家重点实验室(LSL) |
Corresponding Author | Liang YM(梁永民) |
Affiliation | 1.Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China 2.Jiangxi Sci Technol Normal Univ, Jiangxi Key Lab Organ Chem, Nanchang 330013, Peoples R China 3.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Lanzhou 730000, Peoples R China |
Recommended Citation GB/T 7714 | Han, Ya-Ping,Song XR,Qiu, Yi-Feng,et al. Lewis Acid Catalyzed [4+3] Cycloaddition of Propargylic Alcohols with Azides[J]. Organic Letters,2016,18(5):940-943. |
APA | Han, Ya-Ping.,Song XR.,Qiu, Yi-Feng.,Zhang, Heng-Rui.,Li, Lian-Hua.,...&梁永民.(2016).Lewis Acid Catalyzed [4+3] Cycloaddition of Propargylic Alcohols with Azides.Organic Letters,18(5),940-943. |
MLA | Han, Ya-Ping,et al."Lewis Acid Catalyzed [4+3] Cycloaddition of Propargylic Alcohols with Azides".Organic Letters 18.5(2016):940-943. |
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acs.orglett.5b03657.(832KB) | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text |
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