LICP OpenIR  > 羰基合成与选择氧化国家重点实验室(OSSO)
Copper-catalyzed decarboxylative cross-coupling of cinnamic acids and ACCN via single electron transfer
DepartmentOSSO国家重点实验室
Gao B(高宝)1,2; Xie YJ(谢银君)1; Yang L(杨磊)1; Huang HM(黄汉民)1; Huang HM(黄汉民)
2016
Source PublicationOrganic & Biomolecular Chemistry
ISSN1477-0520
Volume14Issue:8Pages:2399-2402
Abstract

A novel and convenient method for the synthesis of β,γ-unsaturated nitriles using ACCN (1,1′-azobis(cyclohexane-1-carbonitrile)) as a cyano source was described. This reaction was amenable to a broad range of substrates and provided the desired β,γ-unsaturated nitriles containing an all-carbon quaternary carbon center in moderate yields with high selectivity via single electron transfer and decarboxylation.

Subject Area物理化学与绿色催化
DOI10.1039/c5ob02677f
Funding Organizationthe Chinese Academy of Sciences;the National Natural Science Foundation of China (21222203;21372231;21133011)
Indexed BySCI
If3.564
Language英语
Funding Project有机功能材料研究组
compositor第一作者单位
Citation statistics
Cited Times:27[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.licp.cn/handle/362003/19755
Collection羰基合成与选择氧化国家重点实验室(OSSO)
Corresponding AuthorHuang HM(黄汉民)
Affiliation1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Gao B,Xie YJ,Yang L,et al. Copper-catalyzed decarboxylative cross-coupling of cinnamic acids and ACCN via single electron transfer[J]. Organic & Biomolecular Chemistry,2016,14(8):2399-2402.
APA Gao B,Xie YJ,Yang L,Huang HM,&黄汉民.(2016).Copper-catalyzed decarboxylative cross-coupling of cinnamic acids and ACCN via single electron transfer.Organic & Biomolecular Chemistry,14(8),2399-2402.
MLA Gao B,et al."Copper-catalyzed decarboxylative cross-coupling of cinnamic acids and ACCN via single electron transfer".Organic & Biomolecular Chemistry 14.8(2016):2399-2402.
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