LICP OpenIR  > 羰基合成与选择氧化国家重点实验室(OSSO)
Straightforward synthesis of functionalized chroman-4-ones through cascade radical cyclization-coupling of 2-(allyloxy)arylaldehydes
DepartmentOSSO国家重点实验室
Zhao JJ(赵静静)1,2; Li P(李盼)1,2; Li XJ(李新建)1; Xia CG(夏春谷)1; Li FW(李福伟)1; Li FW(李福伟)
2016
Source PublicationChemical Communications
ISSN1359-7345
Volume52Issue:18Pages:3661-3664
Abstract

A novel and direct approach to synthesize a series of phosphonate, azide and hydroxy functionalized chroman-4-ones has been developed. The cascade transformation appears to proceed through an intramolecular addition of an in situ generated acyl radical onto the alkene, followed by a selective nucleophilic radical–electrophilic radical cross coupling.

Subject Area物理化学与绿色催化
DOI10.1039/c5cc09730d
Funding Organizationthe Chinese Academy of Sciences;the National Natural Science Foundation of China (21133011;21373246;21522309)
Indexed BySCI
If6.319
Language英语
Funding Project均相催化课题组
compositor第一作者单位
Citation statistics
Cited Times:74[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.licp.cn/handle/362003/19753
Collection羰基合成与选择氧化国家重点实验室(OSSO)
Corresponding AuthorLi FW(李福伟)
Affiliation1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China
2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Zhao JJ,Li P,Li XJ,et al. Straightforward synthesis of functionalized chroman-4-ones through cascade radical cyclization-coupling of 2-(allyloxy)arylaldehydes[J]. Chemical Communications,2016,52(18):3661-3664.
APA Zhao JJ,Li P,Li XJ,Xia CG,Li FW,&李福伟.(2016).Straightforward synthesis of functionalized chroman-4-ones through cascade radical cyclization-coupling of 2-(allyloxy)arylaldehydes.Chemical Communications,52(18),3661-3664.
MLA Zhao JJ,et al."Straightforward synthesis of functionalized chroman-4-ones through cascade radical cyclization-coupling of 2-(allyloxy)arylaldehydes".Chemical Communications 52.18(2016):3661-3664.
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