| Palladium-catalyzed hydroaminocarbonylation of alkenes with amines promoted by weak acid | |
| Department | OSSO国家重点实验室 |
Zhang GY(张国营)1,3 ; Ji, Xiaolei1,2; Yu, Hui1,3; Yang L(杨磊)1,3; Jiao, Peng2; Huang HM(黄汉民)1; Huang HM(黄汉民)
| |
| 2016 | |
| Source Publication | Tetrahedron Letters
 |
| ISSN | 0040-4039 |
| Volume | 57Issue:3Pages:383-386 |
| Abstract | The weak acid has been identified as an efficient basicity-mask to overcome the basicity barrier imparted by aliphatic amines in the Pd-catalyzed hydroaminocarbonylation, which enables both aromatic and aliphatic amines to be applicable in the palladium-catalyzed hydroaminocarbonylation reaction. Notably, by using this protocol, the marketed herbicide of Propanil and drug of Fentanyl could be easily obtained in a one-pot manner. |
| Keyword | Palladium Hydroaminocarbonylation Alkenes Amines Amides |
| Subject Area | 物理化学与绿色催化 |
| DOI | 10.1016/j.tetlet.2015.12.031 |
| Funding Organization | the Chinese Academy of Sciences;the National Natural Science Foundation of China (21222203;21372231;21133011). |
| Indexed By | SCI |
| If | 2.193 |
| Language | 英语 |
| Funding Project | 有机功能材料研究组 |
| compositor | 第一作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/19734 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） |
| Corresponding Author | Jiao, Peng; Huang HM(黄汉民) |
| Affiliation | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China 2.Beijing Normal Univ, Coll Chem, Beijing 100875, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| Recommended Citation GB/T 7714 | Zhang GY,Ji, Xiaolei,Yu, Hui,et al. Palladium-catalyzed hydroaminocarbonylation of alkenes with amines promoted by weak acid[J]. Tetrahedron Letters,2016,57(3):383-386. |
| APA | Zhang GY.,Ji, Xiaolei.,Yu, Hui.,Yang L.,Jiao, Peng.,...&黄汉民.(2016).Palladium-catalyzed hydroaminocarbonylation of alkenes with amines promoted by weak acid.Tetrahedron Letters,57(3),383-386. |
| MLA | Zhang GY,et al."Palladium-catalyzed hydroaminocarbonylation of alkenes with amines promoted by weak acid".Tetrahedron Letters 57.3(2016):383-386. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| 1-s2.0-S004040391530（756KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.
Edit Comment