LICP OpenIR  > 羰基合成与选择氧化国家重点实验室(OSSO)
Palladium-catalysed coupling reaction of aminals with N-sulfonyl hydrazones to give allylic sulfones
DepartmentOSSO国家重点实验室
Li JW(李加文)1,2; Qin GP(秦贵平)1,2; Liu Y(刘洋)1,2; Huang HM(黄汉民)1; Huang HM(黄汉民)
2016
Source PublicationOrganic chemistry frontiers
ISSN2052-4129
Volume3Issue:2Pages:259-267
Abstract

Palladium-catalysed cross-coupling of aminals with N-sulfonyl hydrazones has been established via C–N bond activation under base-free conditions, in which one C–C bond and one C–S bond were simultaneously generated. It was successfully applied in the construction of a variety of aminomethyl substituted allylic sulfones. Preliminary mechanistic studies indicated that the unique electrophilic cyclopalladated complex was involved in the catalytic cycle.

Subject Area物理化学与绿色催化
DOI10.1039/c5qo00381d
Funding Organizationthe National Natural Science Foundation of China (21222203;21372231;21133011);Chinese Academy of Sciences
Indexed BySCI
If4.955
Language英语
Funding Project有机功能材料研究组
compositor第一作者单位
Citation statistics
Cited Times:22[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.licp.cn/handle/362003/19719
Collection羰基合成与选择氧化国家重点实验室(OSSO)
Corresponding AuthorHuang HM(黄汉民)
Affiliation1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Li JW,Qin GP,Liu Y,et al. Palladium-catalysed coupling reaction of aminals with N-sulfonyl hydrazones to give allylic sulfones[J]. Organic chemistry frontiers,2016,3(2):259-267.
APA Li JW,Qin GP,Liu Y,Huang HM,&黄汉民.(2016).Palladium-catalysed coupling reaction of aminals with N-sulfonyl hydrazones to give allylic sulfones.Organic chemistry frontiers,3(2),259-267.
MLA Li JW,et al."Palladium-catalysed coupling reaction of aminals with N-sulfonyl hydrazones to give allylic sulfones".Organic chemistry frontiers 3.2(2016):259-267.
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