| Unexpected formation of novel organometallic hetero-cation crystals with a rare coordination mode | |
| Department | 羰基合成与选择氧化国家重点实验室 |
Deng FG(邓凡果); Hu B(胡斌) ; Sun W(孙伟); Xia CG(夏春谷)
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| 2008 | |
| Source Publication | Dalton Transactions
 |
| ISSN | 1477-9226 |
| Pages | 5957-5961 |
| Abstract | The imitative synthesis of the ionic liquid [bmim][Co(CO)4], carried out in organic solvents instead of water, produced an unexpected liquid complex with partial crystallization. The resulting solid was confirmed to be the novel hetero-cation salt, [bmim]K[Co(CO)4]2 (1) and a crystallographic investigation revealed an extremely unusual (CO)7–K coordination mode. When the organic cation was replaced by [C4Py]+, similar crystallization was also obtained, forming [C4Py]K[Co(CO)4]2 (2), which has an analogous structure. Both of these cases indicate an interesting influence that these organic cations have on the crystallization of organometallic structures that yields new structural examples. |
| Subject Area | 清洁催化与生物转化 |
| Funding Organization | the National Natural Science Foundation of China (projects 20533080;20625308);the Chinese Academy of Sciences |
| Indexed By | SCI |
| Language | 英语 |
| Funding Project | 清洁催化与生物转化研究组 ; 羰基金属功能材料研究组 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/1970 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） |
| Corresponding Author | Sun W(孙伟); Xia CG(夏春谷) |
| Recommended Citation GB/T 7714 | Deng FG,Hu B,Sun W,et al. Unexpected formation of novel organometallic hetero-cation crystals with a rare coordination mode[J]. Dalton Transactions,2008:5957-5961. |
| APA | 邓凡果,胡斌,孙伟,&夏春谷.(2008).Unexpected formation of novel organometallic hetero-cation crystals with a rare coordination mode.Dalton Transactions,5957-5961. |
| MLA | 邓凡果,et al."Unexpected formation of novel organometallic hetero-cation crystals with a rare coordination mode".Dalton Transactions (2008):5957-5961. |
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| 18_Dalton Trans.,200（270KB） | 开放获取 | License | View Application Full Text | |||
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