Kinetic study on the linalool ozonolysis reaction in the atmosphere | |
Department | 固体润滑国家重点实验室 |
Sun XM(孙孝敏)1,2; Zhang CX(张晨熙)1; Zhao YY(赵宇阳)1; Bai J(白静)1; He, Maoxia1 | |
2012 | |
Source Publication | Canadian Journal of Chemistry |
ISSN | 0008-4042 |
Volume | 90Issue:4Pages:353-361 |
Abstract | In the atmosphere, linalool ozonolysis will generate a series of oxidation products and then form particles through nucleation. In this study, the linalool ozonolysis mechanisms were studied and some of the main products detected from experiment are verified. The Rice–Ramsperger–Kassel–Marcus (RRKM) theory and the canonical variational transition state theory (CVT) with small curvature tunneling effect (SCT) are used to calculate rate constants over the temperature range of 200∼800 K. The total rate constant for the reaction of ozone with linalool is 4.50 × 10−16 cm3 molecule–l s–l, and the addition of ozone to (CH3)2C=CH– is the main ozone addition position. Furthermore, the Arrhenius formulas are fitted and the lifetimes of reaction species in the troposphere are discussed for the first time. The total atmospheric lifetime of linalool relative to O3 is 2.30 h. The O3-initiated atmospheric lifetimes of P1, P3, and P6 are 2.64 months, 16.67 days, and 15.5 h, respectively. |
Keyword | Linalool Ozonolysis Reaction Rate Constants Atmospheric Lifetime |
DOI | 10.1139/V2012-001 |
Funding Organization | the National Natural Science Foundation of China (Nos. 20903062;21177076;20873074;20737001);the Natural Science Foundation of Shandong Province (No. Q2008B07);the Independent Innovation Foundation of Shandong University (No. 2010TS064);the Open Project from State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research Center for Eco-Environmental Science, Chinese Academy of Sciences (No. KF2009-10) |
Indexed By | SCI |
If | 0.964 |
Language | 英语 |
compositor | 第二作者单位 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/19498 |
Collection | 固体润滑国家重点实验室(LSL) |
Affiliation | 1.Shandong Univ, Environm Res Inst, Jinan 250100, Peoples R China 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Lanzhou 730000, Peoples R China |
Recommended Citation GB/T 7714 | Sun XM,Zhang CX,Zhao YY,et al. Kinetic study on the linalool ozonolysis reaction in the atmosphere[J]. Canadian Journal of Chemistry,2012,90(4):353-361. |
APA | Sun XM,Zhang CX,Zhao YY,Bai J,&He, Maoxia.(2012).Kinetic study on the linalool ozonolysis reaction in the atmosphere.Canadian Journal of Chemistry,90(4),353-361. |
MLA | Sun XM,et al."Kinetic study on the linalool ozonolysis reaction in the atmosphere".Canadian Journal of Chemistry 90.4(2012):353-361. |
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v2012-001.pdf(120KB) | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text |
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