| Enantioselective Epoxidation of Olefins with H2O2 Catalyzed by Bioinspired Aminopyridine Manganese Complexes | |
| Department | OSSO国家重点实验室 |
Shen DY(沈都益)1,2 ; Qiu B(邱斌)1,2; Xu DQ(徐大乾)1; Miao CX(苗成霞)1; Xia CG(夏春谷)1; Sun W(孙伟)1; Sun W(孙伟)
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| 2016 | |
| Source Publication | Organic Letters
 |
| ISSN | 1523-7060 |
| Volume | 18Issue:3Pages:372-375 |
| Abstract | A novel family of bioinspired manganese(II) complexes bearing chiral aminopyridine ligands that possessed additional aromatic groups and strong donating dimethylamino groups were synthesized and characterized. These manganese complexes exhibited efficient and improved activities in the asymmetric epoxidation of various olefins, such as styrene derivatives (up to 93% ee) with H2O2 as the oxidant, even with a catalytic amount of carboxylic acid as the additive. |
| Subject Area | 物理化学与绿色催化 |
| DOI | 10.1021/acs.orglett.5b03309 |
| Funding Organization | the National Natural Science Foundation of China (21473226;21133011) |
| Indexed By | SCI |
| If | 6.579 |
| Language | 英语 |
| Funding Project | 生物与仿生催化课题组 |
| compositor | 第一作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/19475 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） |
| Corresponding Author | Sun W(孙伟) |
| Affiliation | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| Recommended Citation GB/T 7714 | Shen DY,Qiu B,Xu DQ,et al. Enantioselective Epoxidation of Olefins with H2O2 Catalyzed by Bioinspired Aminopyridine Manganese Complexes[J]. Organic Letters,2016,18(3):372-375. |
| APA | Shen DY.,Qiu B.,Xu DQ.,Miao CX.,Xia CG.,...&孙伟.(2016).Enantioselective Epoxidation of Olefins with H2O2 Catalyzed by Bioinspired Aminopyridine Manganese Complexes.Organic Letters,18(3),372-375. |
| MLA | Shen DY,et al."Enantioselective Epoxidation of Olefins with H2O2 Catalyzed by Bioinspired Aminopyridine Manganese Complexes".Organic Letters 18.3(2016):372-375. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| acs.orglett.5b03309.（773KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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